118067-01-9

Basic information

• Product Name: ethyl 2-benzoyl-4-methylpent-4-enoate
• Synonyms: ethyl 2-benzoyl-4-methylpent-4-enoate
• CAS NO: 118067-01-9
• Molecular Weight: 246.306
• Mol File: 118067-01-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: ethyl 2-benzoyl-4-methylpent-4-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-benzoyl-4-methylpent-4-enoate(118067-01-9)
• EPA Substance Registry System: ethyl 2-benzoyl-4-methylpent-4-enoate(118067-01-9)

Safety Data

• Hazardous Substances Data: 118067-01-9(Hazardous Substances Data)

Upstream product

• 94514-04-2 3-tert-Butylsulfanyl-2-methyl-propene 
• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 563-47-3 3-Chloro-2-methylpropene 
• 1458-98-6 2-methyl-3-bromo-1-propene 

Downstream Products

• 86577-43-7 ethyl 5,5-dimethyl-2-phenyl-4,5-dihydrofuran-3-carboxylate 
• 1078-36-0 4-methyl-1-phenyl-4-pentene-1-one 
• 63942-88-1 (5-methylhexa-1,5-dien-2-yl)benzene 
• 583-05-1 1-phenylpentane-1,4-dione 

Relevant articles and documents

Iodine-Catalyzed Synthesis of Substituted Furans and Pyrans: Reaction Scope and Mechanistic Insights

Substituted pyrans and furans are core structures found in a wide variety of natural products and biologically active compounds. Herein, we report a practical and mild catalytic method for the synthesis of substituted pyrans and furans using molecular iodine, a simple and inexpensive catalyst. The method described is performed under solvent-free conditions at an ambient temperature and atmosphere, thus offering a facile and practical alternative to currently available reaction protocols. A combination of experimental studies and density functional theory calculations revealed interesting mechanistic insights into this seemingly simple reaction.

Iron-catalyzed acylation-functionalization of unactivated alkenes with aldehydes

Herein, an iron-catalyzed acylation-functionalization of unactivated alkenes with aldehydes via distal group ipso-migration is reported. This strategy overcame the energy barrier and reversibility in the difunctionalization of unactivated alkenes with nuc

Enantioselective and Diastereoselective Ir-Catalyzed Hydrogenation of α-Substituted β-Ketoesters via Dynamic Kinetic Resolution

An iridium/f-amphol catalytic system for the enantioselective hydrogenation of α-substituted β-ketoesters via dynamic kinetic resolution is reported. The desired anti products were obtained in high yields (up to 98%) with good diastereoselectivity (up to 96:4 diastereometic ratio (dr)) and excellent enantioselectivity (up to >99% enantiomeric excess (ee)). A catalytic model is proposed to explain the stereoselectivity.