118132-07-3Relevant articles and documents
Amphiphilic [tpy-MII-tpy] metallotriangles: synthesis, characterisation and hierarchical ordering
Ludlow, James M.,Saunders, Mary Jane,Huang, Mingjun,Guo, Zaihong,Moorefield, Charles N.,Cheng, Stephen Z. D.,Wesdemiotis, Chrys,Newkome, George R.
, p. 69 - 79 (2017)
Long chain (C16) alkylated metallocycles are synthesised and characterised. Their ordered aggregation was studied via TEM to gauge to the effects of molecular topology, solvent, counterion and metal centre(s) on morphology and nanoscale structu
Hydrophobic-Driven, Metallomacrocyclic Assembly - Towards Quantitative Construction
Xie, Ting-Zheng,Li, Jing-Yi,Guo, Zaihong,Ludlow, James M.,Lu, Xiaocun,Moorefield, Charles N.,Wesdemiotis, Chrys,Newkome, George R.
, p. 1671 - 1677 (2016/04/26)
A series of coordination-driven, heteroleptic self-assembled, bowtie-shaped bis-macrocycles were designed and constructed by combining tetrakis(terpyridinyl)thianthrene and bis-terpyridine, 60°-directed, Ru2+ dimers. The resulting complexes wer
Control of the Discotic to Isotropic Transition in Alkoxy-Substituted Silicondihydroxo-Phthalocyanines by Axial Substituents
Sauer, Thomas,Wegner, Gerhard
, p. 97 - 118 (2007/10/02)
The synthesis of a homologous series of octaalkoxy-substituted silicondihydroxo-phthalocyanines is described.The mesomorphic properties of these new materials were studied by DSC, optical microscopy and X-ray investigations.Compounds with n >/= 4 (n is the number of carbon atoms in a single alkoxy side chain) show a discotic mesophase transition.A transition to the isotropic state is only observed when n >/= 8.X-ray diffraction patterns of the mesophases confirm that all compounds form a hexagonal columnar mesophase of the type Dhd.