118149-91-0Relevant academic research and scientific papers
Formaldehyde as Tethering Organocatalyst: Highly Diastereoselective Hydroaminations of Allylic Amines
Hesp, Colin R.,MacDonald, Melissa J.,Zahedi, M. Mehdi,Bilodeau, Didier A.,Zhao, Shu-Bin,Pesant, Marc,Beauchemin, André M.
, p. 5136 - 5139 (2015/11/03)
Catalysts possessing sufficient activity to achieve intermolecular alkene hydroaminations under mild conditions are rare, and this likely accounts for the scarcity of asymmetric variants of this reaction. Herein, highly diastereoselective hydroaminations
PALLADIUM(0)-CATALYZED HYDROXYLAMINATION OF ALLYL ESTERS. SYNTHESIS OF N-ALLYLHYDROXYLAMINES AND SECONDARY ALLYLAMINES
Murahashi, Shun-Ichi,Imada, Yasushi,Taniguchi, Yuki,Kodera, Yoichi
, p. 2973 - 2976 (2007/10/02)
Palladium-catalyzed reaction of allyl esters with hydroxylamines gives N-allylhydroxylamines, which are readily converted into secondary allylamines upon treatment with zinc powder in a dilute HCl solution.
