118149-99-8Relevant academic research and scientific papers
Synthesis of the bridging framework of phragmalin-type limonoids
Lebold, Terry P.,Gallego, Gary M.,Marth, Christopher J.,Sarpong, Richmond
supporting information; experimental part, p. 2110 - 2113 (2012/07/03)
An efficient synthesis of the octahydro-1H-2,4-methanoindene core of phragmalin-type limonoids, such as xyloccensins O and P, is reported. The success of the synthetic route is predicated on the use of network analysis in the retrosynthetic analysis and a
Limitations of the two-phase doebner-miller reaction for the synthesis of quinolines
Reynolds, Kristie A.,Young, David J.,Loughlin, Wendy A.
experimental part, p. 3645 - 3648 (2010/12/19)
The Doebner-Miller synthesis of quinolines under modified biphasic conditions was investigated. Crotonaldehyde, reacted readily with aniline to produce 2-methylquinoline. However, cinnamaldehyde and other γ-substituted α,β-unsaturated aldehydes yielded complex mixtures with substituted anilines to provide only trace quantities of quinolines. The Doebner-Miller reaction under these conditions is only suitable for sterically accessible α,β-unsaturated aldehydes.
Polymer Supported Perruthenate (PSP): A new oxidant for clean organic synthesis
Hinzen, Berthold,Ley, Steven V.
, p. 1907 - 1908 (2007/10/03)
A polymer supported perruthenate reagent has been prepared and used in the conversion of primary and secondary alcohols to aldehydes and ketones, respectively, affording pure products without the need for conventional work-up procedures.
AN EFFICIENT METHOD FOR THE PREPARATION OF ALKYLIDENECYCLOPROPANES
Stafford, Jeffrey A.,McMurry, John E.
, p. 2531 - 2534 (2007/10/02)
Yields obtained from Wittig reactions with cyclopropylidenetriphenylphosporane are greatly improved by addition of the phase-transfer catalyst, TDA-1.
