118157-80-5

Basic information

• Product Name: N-((E)-1-Ethyl-but-2-enyl)-4-methyl-benzenesulfonamide
• Synonyms: N-((E)-1-Ethyl-but-2-enyl)-4-methyl-benzenesulfonamide
• CAS NO: 118157-80-5
• Molecular Weight: 253.365
• Mol File: 118157-80-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-((E)-1-Ethyl-but-2-enyl)-4-methyl-benzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-((E)-1-Ethyl-but-2-enyl)-4-methyl-benzenesulfonamide(118157-80-5)
• EPA Substance Registry System: N-((E)-1-Ethyl-but-2-enyl)-4-methyl-benzenesulfonamide(118157-80-5)

Safety Data

• Hazardous Substances Data: 118157-80-5(Hazardous Substances Data)

Upstream product

• 7688-21-3 cis-2-hexene 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 4050-45-7 trans-2-hexene 
• 13269-52-8 trans-3-Hexene 
• 55962-05-5 4-methyl-N-[(E)-phenyl-λ³-iodanylidene]benzenesulfonamide 

Relevant articles and documents

Amidation of saturated C-H bonds catalyzed by electron-deficient ruthenium and manganese porphyrins. A highly catalytic nitrogen atom transfer process

(equation presented) Amidation of a variety of hydrocarbons with PhI=NTs catalyzed by ruthenium and manganese meso-tetrakis(pentafluorophenyl)porphyrins 1 and 2 afforded N-substituted amides in up to 92% yields with good to excellent substrate conversions. By employing catalyst 2, exceptionally high turnovers (up to 2600) were achieved, and the amidations can be effected by directly using PhI(OAc)2/NH2R as amidating reagents; in the case of R = COCF3 a direct amination was realized in up to 90% yield.