118157-80-5Relevant academic research and scientific papers
Amidation of saturated C-H bonds catalyzed by electron-deficient ruthenium and manganese porphyrins. A highly catalytic nitrogen atom transfer process
Yu, Xiao-Qi,Huang, Jie-Sheng,Zhou, Xiang-Ge,Che, Chi-Ming
, p. 2233 - 2236 (2007/10/03)
(equation presented) Amidation of a variety of hydrocarbons with PhI=NTs catalyzed by ruthenium and manganese meso-tetrakis(pentafluorophenyl)porphyrins 1 and 2 afforded N-substituted amides in up to 92% yields with good to excellent substrate conversions. By employing catalyst 2, exceptionally high turnovers (up to 2600) were achieved, and the amidations can be effected by directly using PhI(OAc)2/NH2R as amidating reagents; in the case of R = COCF3 a direct amination was realized in up to 90% yield.
ALLYLIC AMINATION OF ALKENES BY TOSYLIMINOIODOBENZENE : MANGANESE PORPHYRINS AS SUITABLE CATALYSTS
Mahy, J. P.,Bedi, G.,Battioni, P.,Mansuy, D.
, p. 1927 - 1930 (2007/10/02)
Manganese-porphyrins and particularly Mn(TPP)(ClO4) were found to be much better catalysts than iron-porphyrins for allylic N-tosylamination of alkenes by tosyliminoiodobenzene.With the former catalyst, cyclohexene was selectively transformed into 3-tosyl
