118160-44-4

Basic information

• Product Name: 2-(PHENYLSULFONYL)-1 3-CYCLOHEPTADIENE
• Synonyms: 2-(Phenylsulfonyl)-1,3-cycloheptadiene
• CAS NO: 118160-44-4
• Molecular Formula: C₁₃H₁₄O₂S
• Molecular Weight: 234.31
• Product Categories: Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfones;Sulfur Compounds
• Mol File: 118160-44-4.mol

Chemical Properties

• Melting Point: 60-64 °C(lit.)
• Appearance: /
• CAS DataBase Reference: 2-(PHENYLSULFONYL)-1 3-CYCLOHEPTADIENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(PHENYLSULFONYL)-1 3-CYCLOHEPTADIENE(118160-44-4)
• EPA Substance Registry System: 2-(PHENYLSULFONYL)-1 3-CYCLOHEPTADIENE(118160-44-4)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 118160-44-4(Hazardous Substances Data)

Usage

Uses

Used in Organic Chemistry:
2-(PHENYLSULFONYL)-1,3-CYCLOHEPTADIENE serves as a versatile building block for the synthesis of a diverse array of organic compounds. Its capacity to participate in various chemical reactions, such as Diels-Alder reactions and radical reactions, underscores its utility in creating complex organic molecules.
Used in Synthesis of Complex Organic Molecules:
The unique structure of 2-(PHENYLSULFONYL)-1,3-CYCLOHEPTADIENE, combined with its reactivity, positions it as an indispensable tool in the synthesis of complex organic molecules. Its ability to engage in a range of chemical transformations facilitates the construction of intricate molecular architectures.
Used in Functional Group Transformations:
The sulfonyl group present in 2-(PHENYLSULFONYL)-1,3-CYCLOHEPTADIENE is amenable to various functional group transformations. This feature broadens the compound's potential applications in organic synthesis, allowing for the development of novel compounds with tailored properties for specific applications across different industries.

Upstream product

• 876938-53-3 Cyclohepta-1,3-diene 
• 60805-71-2 phenylselenyl benzenesulfonate 
• 502-42-1 cycloheptanone 
• 108-98-5 thiophenol 
• 64741-11-3 1-cycloheptenyl phenyl sulfide 
• 396729-08-1 1-(phenylsulfonyl)-7-bromocycloheptene 

Downstream Products

• 131179-54-9 trans-4-n-butyl-3-(phenylsulfonyl)cycloheptene 
• 131179-54-9 cis-4-n-butyl-3-(phenylsulfonyl)cycloheptene 
• 474023-09-1 (3-benzenesulfonyl-cyclohepta-2,4-dienyloxy)-tert-butyl-dimethyl-silane 
• 1060217-80-2 (S)-3-Benzenesulfonyl-cyclohepta-2,4-dienol 
• 474094-59-2 (1S,7S)-(2-phenylsulfonyl)-8-oxabicyclo[5.1.0]oct-2-ene 
• 773148-44-0 (1R,7R)-(2-phenylsulfonyl)-8-oxabicyclo[5.1.0]oct-2-ene 

Relevant articles and documents

Improved and environmentally friendly large-scale preparation of cyclohexadienyl-, cycloheptadienyl sulfone and enantiopure epoxy cycloheptyl sulfones

Kilogram-scale amounts of cycloheptadienyl phenylsulfone and cyclohexadienyl phenylsulfone were prepared by one operation in 5 stages with over 50% yield and requiring no purification. A practical and efficient method for the Jacobsen asymmetric epoxidati

Economical and environmentally friendly syntheses of 2-(phenylsulfonyl)-1,3-cyclohexadiene and 2-(phenylsulfonyl)-1,3-cycloheptadiene

A large-scale and inexpensive synthesis of dienes 1 and 2 has been developed via a four-step procedure starting with benzenethiol and the corresponding cyclic ketone. No chromatography is required.

SELENOSULFONATION OF 1,3-DIENES: ONE-POT SYNTHESIS OF 2-(PHENYLSULFONYL)-1,3-DIENES

A one-pot procedure for the transformation of a 1,3-diene into the corresponding 2-(phenylsulfonyl)-1,3-diene was developed.The reaction involves a 1,2-selenosulfonation-oxidation sequence.