118163-42-1Relevant articles and documents
Alternating oligo(o,p-phenylenes) via ruthenium catalyzed diol-diene benzannulation: orthogonality to cross-coupling enables de novo nanographene and PAH construction
Kasun, Zachary A.,Sato, Hiroki,Nie, Jing,Mori, Yasuyuki,Bender, Jon A.,Roberts, Sean T.,Krische, Michael J.
, p. 7866 - 7873 (2018)
Ruthenium(0) catalyzed diol-diene benzannulation is applied to the conversion of oligo(p-phenylene vinylenes) 2a-c, 5 and 6 to alternating oligo(o,p-phenylenes) 10a-c, 11-13. Orthogonality with respect to conventional palladium catalyzed biaryl cross-coup
REDUCTION OF BIS-1,2-DIKETONES
Bakibaev, A. A.,Savchenko, T. I.,Filimonov, V. D.,Ketskalo, V. M.
, p. 697 - 699 (2007/10/02)
The reduction of bis-1,2-diketones was realized with sodium borohydride.An assessment of the effect of the structure on the reactivity is given.It was found that 1,4-di(2-phenyl-1,2-dioxoethyl)benzene has high reactivity, and the possibility of its full reduction or selective reduction at only one reaction center was demonstrated.The meso form of the obtained diol was established by means of the data from PMR spectroscopy.