118171-25-8Relevant articles and documents
Regio- and Stereoselective Oxysulfonylation of Allenes
Huang, Zhiyuan,Lu, Qingquan,Liu, Yichang,Liu, Dong,Zhang, Jian,Lei, Aiwen
supporting information, p. 3940 - 3943 (2016/08/30)
A highly regio- and stereoselective oxysulfonylation of allenes was developed that provided direct access to 2-sulfonyl allylic alcohols in good yields. By means of dioxygen activation, selective difunctionlization of allenes could be successfully achieved under mild metal-free conditions. Preliminary mechanistic investigation disclosed that this transformation probably goes through a radical process.