1503-99-7

Basic information

• Product Name: 4-Pentenoic acid, 3-oxo-5-phenyl-, ethyl ester
• CAS NO: 1503-99-7
• Molecular Formula: C13H14O3
• Molecular Weight: 218.252
• Mol File: 1503-99-7.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: 4-Pentenoic acid, 3-oxo-5-phenyl-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Pentenoic acid, 3-oxo-5-phenyl-, ethyl ester(1503-99-7)
• EPA Substance Registry System: 4-Pentenoic acid, 3-oxo-5-phenyl-, ethyl ester(1503-99-7)

Safety Data

• Hazardous Substances Data: 1503-99-7(Hazardous Substances Data)

Upstream product

• 13148-05-5 ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate 
• 100-52-7 benzaldehyde 
• 76352-65-3 ethyl (E)-2-acetyl-3-oxo-5-phenylpent-4-enoate 
• 64-19-7 acetic acid 
• 102-92-1 Cinnamoyl chloride 
• 27271-34-7 (2-ethoxy-3-ethoxycarbonyl-2-propenylidene)triphenylphosphorane 
• 6082-74-2 4,4-dichloro-3-oxobutyric acid ethyl ester 
• 27271-29-0 3-Aethoxy-5-phenyl-2,4-pentadiensaeure-aethylester 
• 14371-10-9 (E)-3-phenylpropenal 
• 623-73-4 diazoacetic acid ethyl ester 
• 118171-25-8 ethyl 3-(phenylsulfonyl)but-3-enoate 
• 14369-81-4 ethyl 2,3-butadienoate 
• 141-97-9 ethyl acetoacetate 
• 17071-33-9 racemic ethyl 5-hydroxy-3-oxo-5-phenylpentanoate 

Downstream Products

• 1270044-06-8 1-(pyridin-2-yl)-3-styryl-1H-pyrazol-5-ol 
• 55629-96-4 ethyl 4-phenyl-2-oxobut-3-enoate 
• 17071-29-3 ethyl 3-oxo-5-phenylpentanoate 

Relevant articles and documents

-

-

Ethyl 4-(diethoxyphosphinyl)-3-oxobutanoate: Selective synthesis of β-keto phosphonates

The selective synthesis of ethyl 4-(diethoxyphosphinyl)-3-oxobutanoate (7) and the utilization of its trimethylsilyl enolether (14) in a tandem desilylation Horner-Wittig condensation is illustrated.

Efficient Synthesis of Functionalized β-Keto Esters and β-Diketones through Regioselective Hydration of Alkynyl Esters and Alkynyl Ketones by Use of a Cationic NHC–AuICatalyst

Regioselective hydration of α-alkynyl esters and ketones by using a cationic NHC–AuIcatalyst results in β-keto esters and β-diketones, respectively. Controlled release of water in acetone by aldol self-condensation under the reaction conditions makes acetone as better solvent than 1,4-dioxane/water for the hydration of α-alkynyl esters having sensitive ester moieties.

Oxone-mediated oxidative cleavage of β-keto esters and 1,3-diketones to α-keto esters and 1,2-diketones in aqueous medium

A versatile and highly efficient method for the direct synthesis of α-keto esters and 1,2-diketones has been developed. This approach utilizes the oxidative cleavage of a variety of β-keto esters and 1,3-diketones mediated by an Oxone/aluminum trichloride system. The simple one-step oxidation reaction proceeded selectively in aqueous media to afford products in high yields, short reaction times, and environmentally benign conditions.