118203-99-9

Basic information

• Product Name: methyl 2,3-O-isopropylidene-β-D-xylopyranoside
• Synonyms: methyl 2,3-O-isopropylidene-β-D-xylopyranoside
• CAS NO: 118203-99-9
• Molecular Weight: 204.223
• Mol File: 118203-99-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2,3-O-isopropylidene-β-D-xylopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-O-isopropylidene-β-D-xylopyranoside(118203-99-9)
• EPA Substance Registry System: methyl 2,3-O-isopropylidene-β-D-xylopyranoside(118203-99-9)

Safety Data

• Hazardous Substances Data: 118203-99-9(Hazardous Substances Data)

Upstream product

• 65820-93-1 (methyl 2,3-O-isopropylidene-β-D-erythro-pentopyranosid)-4-ulose 
• 1613160-41-0 methyl 2,3-O-isopropylidene-β-D-threo-pentopyranosid-4-ulose 
• 116-11-0 2-Methoxypropene 
• 91-09-8 methyl β-D-ribopyranoside 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 2495-99-0 methyl 2,3-O-isopropylidene-β-D-ribopyranoside 
• 1338548-65-4 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-2,3-O-isopropylidene-β-D-xylopyranoside 
• 1338548-89-2 methyl 2,3-di-O-acetyl-4,6-O-benzylidene-α-D-mannopyranosyl-(1->4)-2,3-di-O-acetyl-β-D-xylopyranosyl-(1->4)-6-O-benzyl-2,3-di-O-acetyl-α-D-mannopyranosyl-(1->4)-2,3-di-O-acetyl-β-D-xylopyranoside 
• 1338548-88-1 methyl 2,3-di-O-acetyl-6-O-benzyl-α-D-mannopyranosyl-(1->4)-2,3-di-O-acetyl-β-D-xylopyranoside 
• 1338548-87-0 methyl 2,3-di-O-acetyl-4,6-O-benzylidene-α-D-mannopyranosyl-(1->4)-2,3-di-O-acetyl-β-D-xylopyranoside 
• 1338548-81-4 methyl 2-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-2,3-di-O-acetyl-β-D-xylopyranoside 
• 1338548-80-3 methyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2-naphthalenylmethyl)-β-D-mannopyranosyl-(1->4)-2,3-di-O-acetyl-β-D-xylopyranoside 
• 1338548-69-8 methyl 2,3,6-tri-O-benzyl-β-D-mannopyranosyl-(1->4)-2,3-di-O-benzoyl-β-D-xylopyranoside 
• 1338548-67-6 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-2,3-di-O-benzoyl-β-D-xylopyranoside 
• 1338548-91-6 methyl 2,4-di-O-acetyl-6-O-benzyl-3-O-(2-naphthalenylmethyl)-α-D-mannopyranosyl-(1->4)-2,3-O-isopropylidene-β-D-xylopyranoside 
• 1338548-79-0 methyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2-naphthalenylmethyl)-β-D-mannopyranosyl-(1->4)-2,3-O-isopropylidene-β-D-xylopyranoside 
• 1338548-85-8 methyl 2,3-di-O-acetyl-4,6-O-benzylidene-α-D-mannopyranosyl-(1->4)-2,3-O-isopropylidene-β-D-xylopyranoside 
• 137232-55-4 methyl 3-O-benzoyl-4-O-benzyl-β-D-xylopyranoside 
• 83158-29-6 methyl O⁴-benzoyl-β-D-xyloside 

Relevant articles and documents

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Bio-inspired synthesis of rare and unnatural carbohydrates and cyclitols through strain driven epimerization

We report a bio-inspired, strain driven epimerization of trans-ketals to cis-ketals through an enolate intermediate. Swern oxidation of a hydroxyl group adjacent to a trans-ketal effects both oxidation and its epimerization to cis-ketal. This novel and general strategy allows inversion of up to three contiguous stereocenters and has been illustrated by the synthesis of several unnatural/rare isomers of carbohydrates/cyclitols from their naturally abundant isomers. This journal is the Partner Organisations 2014.

A CONVENIENT METHOD FOR THE PREPARATION OF METHYL 2-DEOXY-β-D-ERYTHRO-PENTOPYRANOSIDE

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