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2-Methoxypropene
Cas No: 116-11-0
USD $ 2.0-2.0 / Kilogram 1 Kilogram 1-10 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
2-Methoxypropene high purity CAS NO. 116-11-0
Cas No: 116-11-0
USD $ 400.0-420.0 / Kilogram 10 Kilogram 10 Metric Ton/Week Xi'an SENYI New Material Technology Co., Ltd Contact Supplier
High quality 2-Methoxypropene supplier in China
Cas No: 116-11-0
No Data 1 Metric Ton 30 Metric Ton/Month Simagchem Corporation Contact Supplier
High purity Various Specifications 2-Methoxypropene CAS:116-11-0
Cas No: 116-11-0
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
2-Methoxypropene
Cas No: 116-11-0
USD $ 12.0-12.0 / Kilogram 1 Kilogram 500 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier
2-Methoxypropene
Cas No: 116-11-0
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Factory Supply Isopropenyl methyl ether
Cas No: 116-11-0
No Data 1 1 Ality Chemical Corporation Contact Supplier
Amadis Chemical offer CAS#116-11-0;CAT#A803557
Cas No: 116-11-0
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
2-Methoxypropene
Cas No: 116-11-0
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 2500 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
Factory direct supply CAS 116-11-0 with best quality
Cas No: 116-11-0
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier

116-11-0 Usage

Chemical Properties

clear colorless liquid
InChI:InChI=1/C4H8O/c1-4(2)5-3/h1H2,2-3H3

116-11-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (I0303)  2-Methoxypropene  >95.0%(GC) 116-11-0 25mL 230.00CNY Detail
TCI America (I0303)  2-Methoxypropene  >95.0%(GC) 116-11-0 100mL 630.00CNY Detail
TCI America (I0303)  2-Methoxypropene  >95.0%(GC) 116-11-0 500mL 1,890.00CNY Detail
Alfa Aesar (B24083)  2-Methoxypropene, 95%, stab. with ca 0.5% potassium carbonate    116-11-0 50g 481.0CNY Detail
Alfa Aesar (B24083)  2-Methoxypropene, 95%, stab. with ca 0.5% potassium carbonate    116-11-0 250g 813.0CNY Detail
Sigma-Aldrich (72537)  2-Methoxypropene  analytical standard 116-11-0 72537-1ML-F 255.06CNY Detail
Aldrich (174645)  2-Methoxypropene  97% 116-11-0 174645-50G 340.47CNY Detail
Aldrich (174645)  2-Methoxypropene  97% 116-11-0 174645-250G 810.81CNY Detail

116-11-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Methoxypropene

1.2 Other means of identification

Product number -
Other names 2-methoxyprop-1-ene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:116-11-0 SDS

116-11-0Synthetic route

methanol
67-56-1

methanol

prop-1-yne
74-99-7

prop-1-yne

2-Methoxypropene
116-11-0

2-Methoxypropene

Conditions
ConditionsYield
With potassium tert-butylate In 1-methyl-pyrrolidin-2-one at 120℃;97%
With potassium hydroxide at 220℃;
2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

2-Methoxypropene
116-11-0

2-Methoxypropene

Conditions
ConditionsYield
With quinoline at 30 - 105℃; under 12751.3 Torr; Temperature; Pyrolysis;93.6%
With quinoline; toluene-4-sulfonic acid at 90℃; for 9h; Catalytic behavior; Reagent/catalyst; Temperature;92.8%
With (trimethylsilyl)manganese pentacarbonyl In acetonitrile at 50℃; for 2h; Mechanism;77 % Spectr.
carbon dioxide
124-38-9

carbon dioxide

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

acetone
67-64-1

acetone

C

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

Conditions
ConditionsYield
With dibutyldimethoxytin at 180℃; under 1520000 Torr; for 24h; Product distribution; metal-catalyzed reaction of acetals with CO2; effect of catalyst structure; effect of additives; pressure effect; possible mechanism;A n/a
B 85%
C 88%
1,2-propanediene
463-49-0

1,2-propanediene

prop-1-yne
74-99-7

prop-1-yne

2-Methoxypropene
116-11-0

2-Methoxypropene

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; potassium tert-butylate In methanol60%
In methanol47%
methylene
2465-56-7

methylene

acetone
67-64-1

acetone

A

2-methyl-1,2-epoxypropane
558-30-5

2-methyl-1,2-epoxypropane

B

2,2,4,4-tetramethyl-[1,3]dioxolane
13372-34-4

2,2,4,4-tetramethyl-[1,3]dioxolane

C

2-Methoxypropene
116-11-0

2-Methoxypropene

D

butanone
78-93-3

butanone

pyridine
110-86-1

pyridine

t-butyl heptafluoroperoxybutyrate
91481-65-1

t-butyl heptafluoroperoxybutyrate

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

tert-butyl heptafluorobutyrate
425-24-1

tert-butyl heptafluorobutyrate

C

pyridinium heptafluorobutyrate
95682-68-1

pyridinium heptafluorobutyrate

D

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

Conditions
ConditionsYield
In toluene at 85℃; for 7h; Yield given. Further byproducts given. Yields of byproduct given;
pyridine
110-86-1

pyridine

t-butyl heptafluoroperoxybutyrate
91481-65-1

t-butyl heptafluoroperoxybutyrate

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

tert-butyl heptafluorobutyrate
425-24-1

tert-butyl heptafluorobutyrate

C

pyridinium heptafluorobutyrate
95682-68-1

pyridinium heptafluorobutyrate

D

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

E

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
In toluene at 65 - 85℃; for 7h; Rate constant; Kinetics; Thermodynamic data; ΔH(act.), ΔS(act.), various temperature;
methanol
67-56-1

methanol

1,2-propanediene
463-49-0

1,2-propanediene

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

C

acetone
67-64-1

acetone

Conditions
ConditionsYield
sodium hydroxide at 190℃; Rate constant; other temperatures;
2-acyl-2,3-dimethyl-3-methoxyoxetane
99797-07-6

2-acyl-2,3-dimethyl-3-methoxyoxetane

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

dimethylglyoxal
431-03-8

dimethylglyoxal

Conditions
ConditionsYield
In various solvent(s) Product distribution; Irradiation; infrared multiphoton induced photolysis; the luminescence of the reaction mixture was also investigated;
t-butyl heptafluoroperoxybutyrate
91481-65-1

t-butyl heptafluoroperoxybutyrate

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

2-Methoxypropene
116-11-0

2-Methoxypropene

C

acetic acid methyl ester
79-20-9

acetic acid methyl ester

D

2-(1-methoxy-1-methylethoxy)-2-methylpropane

2-(1-methoxy-1-methylethoxy)-2-methylpropane

Conditions
ConditionsYield
In pyridine at 50℃; for 12h; Product distribution;A 0.91 % Turnov.
B 0.46 % Turnov.
C 0.03 % Turnov.
D 0.21 % Turnov.
t-butyl heptafluoroperoxybutyrate
91481-65-1

t-butyl heptafluoroperoxybutyrate

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

2-Methoxypropene
116-11-0

2-Methoxypropene

C

tert-butyl heptafluorobutyrate
425-24-1

tert-butyl heptafluorobutyrate

D

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

E

1-methoxy-1-methylethyl heptafluorobutyrate

1-methoxy-1-methylethyl heptafluorobutyrate

Conditions
ConditionsYield
In nitrobenzene at 70℃; for 7h; Product distribution;A 0.90 % Turnov.
B 0.19 % Turnov.
C 0.02 % Turnov.
D 0.06 % Turnov.
E 0.05 % Turnov.
t-butyl heptafluoroperoxybutyrate
91481-65-1

t-butyl heptafluoroperoxybutyrate

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

Di-t-butyl ketone
815-24-7

Di-t-butyl ketone

C

2-Methoxypropene
116-11-0

2-Methoxypropene

D

tert-butyl heptafluorobutyrate
425-24-1

tert-butyl heptafluorobutyrate

E

acetone
67-64-1

acetone

Conditions
ConditionsYield
With pyridine In benzene at 80℃; for 11h; Thermodynamic data; Rate constant; Product distribution; ΔH(excit.); ΔS(excit.); further solvents (octane, nitrobenzene, pyridine, methoxybenzene); other temperature;A 0.63 % Turnov.
B 0.04 % Turnov.
C 0.15 % Turnov.
D 0.02 % Turnov.
E 0.02 % Turnov.
methanol
67-56-1

methanol

1,2-propanediene
463-49-0

1,2-propanediene

prop-1-yne
74-99-7

prop-1-yne

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
sodium hydroxide; pyrographite at 150℃; Rate constant; Thermodynamic data; other temperatures; various molar ratios; other catalyst composition;
methanol
67-56-1

methanol

prop-1-yne
74-99-7

prop-1-yne

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

C

acetone
67-64-1

acetone

Conditions
ConditionsYield
sodium hydroxide at 190℃; Rate constant; other temperatures;
1-Butoxy radical
19062-98-7

1-Butoxy radical

A

2,3-dihydro-2H-furan
1191-99-7

2,3-dihydro-2H-furan

B

4-butanolide
96-48-0

4-butanolide

C

n-propyl hydroperoxide
6068-96-8

n-propyl hydroperoxide

D

2-Methoxypropene
116-11-0

2-Methoxypropene

E

butyraldehyde
123-72-8

butyraldehyde

F

butan-1-ol
71-36-3

butan-1-ol

Conditions
ConditionsYield
With oxygen at 69.9 - 229.9℃; Product distribution; Rate constant; Thermodynamic data; flow and static experiments; isomerization reactions in oxygen; oxidation, isomerization and decomposition; effect of reaction vessel wall conditions; reaction mechanism;
methyl bromide
74-83-9

methyl bromide

acetone enolate ion
24262-31-5

acetone enolate ion

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

butanone
78-93-3

butanone

C

Br(1-)

Br(1-)

Conditions
ConditionsYield
In gas at 39.9℃; Rate constant;
t-butyl heptafluoroperoxybutyrate
91481-65-1

t-butyl heptafluoroperoxybutyrate

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

2-Methoxypropene
116-11-0

2-Methoxypropene

C

tert-butyl heptafluorobutyrate
425-24-1

tert-butyl heptafluorobutyrate

D

acetone
67-64-1

acetone

E

methoxytoluene

methoxytoluene

Conditions
ConditionsYield
With methoxybenzene at 70℃; for 7h; Product distribution;A 0.59 % Turnov.
B 0.14 % Turnov.
C 0.28 % Turnov.
D 0.07 % Turnov.
E n/a
methanol
67-56-1

methanol

1,2-propanediene
463-49-0

1,2-propanediene

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

prop-1-yne
74-99-7

prop-1-yne

2-Methoxypropene
116-11-0

2-Methoxypropene

Conditions
ConditionsYield
at 170℃; under 5250.53 Torr;
methanol
67-56-1

methanol

1,2-propanediene
463-49-0

1,2-propanediene

prop-1-yne
74-99-7

prop-1-yne

2-Methoxypropene
116-11-0

2-Methoxypropene

Conditions
ConditionsYield
ZnO/SiO2 catalyst at 180 - 200℃; under 2625.26 Torr; Product distribution / selectivity; Gas phase;
acetone
67-64-1

acetone

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

A

3,5,5-Trimethylcyclohex-2-en-1-one
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

B

4-methyl-pent-3-en-2-one
141-79-7

4-methyl-pent-3-en-2-one

C

2-Methoxypropene
116-11-0

2-Methoxypropene

D

4-Hydroxy-4-methyl-2-pentanone
123-42-2

4-Hydroxy-4-methyl-2-pentanone

E

acetoacetic acid methyl ester
105-45-3

acetoacetic acid methyl ester

Conditions
ConditionsYield
With CO2 adsorbed on sodium doped MgO at 240℃; for 5h;
2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride
854045-93-5

2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride

C24H35AuOP

C24H35AuOP

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

F6Sb(1-)*C40H54Au2ClP2(1+)

F6Sb(1-)*C40H54Au2ClP2(1+)

Conditions
ConditionsYield
In dichloromethane-d2 at -78 - -65℃; for 0.175h; Equilibrium constant; Glovebox; Cooling with acetone-dry ice;
acetic acid methyl ester
79-20-9

acetic acid methyl ester

Methyltriphenylphosphonium bromide
1779-49-3

Methyltriphenylphosphonium bromide

2-Methoxypropene
116-11-0

2-Methoxypropene

Conditions
ConditionsYield
Stage #1: Methyltriphenylphosphonium bromide With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere;
Stage #2: acetic acid methyl ester In tetrahydrofuran at 20℃; Inert atmosphere;
methanol
67-56-1

methanol

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

A

tetramethylorthosilicate
681-84-5

tetramethylorthosilicate

B

2-Methoxypropene
116-11-0

2-Methoxypropene

C

acetone
67-64-1

acetone

Conditions
ConditionsYield
With carbon dioxide; silica gel; potassium hydroxide at 240℃; under 15001.5 Torr; for 24h; Autoclave;A 83 %Chromat.
B 7 %Chromat.
C 27 %Chromat.
2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

A

2-Methoxypropene
116-11-0

2-Methoxypropene

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With silica gel; potassium hydroxide In methanol at 240℃; under 15001.5 Torr; for 24h; Autoclave;A 7 %Chromat.
B 10 %Chromat.
(E)-3-phenylpropenal
14371-10-9

(E)-3-phenylpropenal

2-Methoxypropene
116-11-0

2-Methoxypropene

[(E)-5-Methoxy-3-(1-methoxy-1-methyl-ethoxy)-hexa-1,5-dienyl]-benzene
148587-30-8

[(E)-5-Methoxy-3-(1-methoxy-1-methyl-ethoxy)-hexa-1,5-dienyl]-benzene

Conditions
ConditionsYield
With tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; acetic acid In dichloromethane for 18h; Ambient temperature;100%
With tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; silica gel; acetic acid at 25℃;83%
With silica gel; acetic acid; tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium In dichloromethane at 25℃; Addition;83%
2-Methoxypropene
116-11-0

2-Methoxypropene

ethyl 3-bromo-2-(hydroxyimino)propanoate
73472-94-3

ethyl 3-bromo-2-(hydroxyimino)propanoate

ethyl 3-bromo-2-<(1-methoxy-1-methylethoxy)imino>propanoate
113512-76-8

ethyl 3-bromo-2-<(1-methoxy-1-methylethoxy)imino>propanoate

Conditions
ConditionsYield
In dichloromethane for 6h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(1S,2R)-1-((4R,5S)-5-Benzhydryloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propane-1,2-diol
128990-37-4

(1S,2R)-1-((4R,5S)-5-Benzhydryloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propane-1,2-diol

(4S,5S,4'R,5'R)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]
86363-80-6

(4S,5S,4'R,5'R)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]

Conditions
ConditionsYield
With (+)-10-camphorsulfonic acid In dichloromethane for 0.5h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(3RS,4S)-4-<(tert-butyloxy)carbonyl>-5-(cyclohexylmethyl)-3-hydroxy-1-pentene
104856-05-5, 104856-06-6, 114457-57-7, 147373-31-7

(3RS,4S)-4-<(tert-butyloxy)carbonyl>-5-(cyclohexylmethyl)-3-hydroxy-1-pentene

3-<(tert-butyloxy)carbonyl>-4-(cyclohexylmethyl)-2,2-dimethyl-5-vinyloxazolidine
122226-01-1

3-<(tert-butyloxy)carbonyl>-4-(cyclohexylmethyl)-2,2-dimethyl-5-vinyloxazolidine

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane for 1h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(3R,4S)-(t-butyloxycarbonyl)-4-amino-3-hydroxy-6-methylheptanoic acid ethyl ester
67010-44-0

(3R,4S)-(t-butyloxycarbonyl)-4-amino-3-hydroxy-6-methylheptanoic acid ethyl ester

(4S,5R)-N-Boc-5-(carbethoxymethyl)-2,2-dimethyl-4-(2-methylpropyl)-1,3-oxazolidine
105018-84-6

(4S,5R)-N-Boc-5-(carbethoxymethyl)-2,2-dimethyl-4-(2-methylpropyl)-1,3-oxazolidine

Conditions
ConditionsYield
With trichlorophosphate for 16h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

3-Benzylidene-1,5-dioxa-spiro[5.5]undecane-2,4-dione
131119-24-9

3-Benzylidene-1,5-dioxa-spiro[5.5]undecane-2,4-dione

C20H24O5

C20H24O5

Conditions
ConditionsYield
at 0℃; for 0.333333h;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

3-(4-Chloro-benzylidene)-1,5-dioxa-spiro[5.5]undecane-2,4-dione
131119-25-0

3-(4-Chloro-benzylidene)-1,5-dioxa-spiro[5.5]undecane-2,4-dione

C20H23ClO5

C20H23ClO5

Conditions
ConditionsYield
at 0℃; for 0.333333h;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

3-(4-Nitro-benzylidene)-1,5-dioxa-spiro[5.5]undecane-2,4-dione
131119-26-1

3-(4-Nitro-benzylidene)-1,5-dioxa-spiro[5.5]undecane-2,4-dione

C20H23NO7

C20H23NO7

Conditions
ConditionsYield
at 0℃; for 0.333333h;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

3-chlorobutan-2-ol
884594-17-6

3-chlorobutan-2-ol

(S)-2-Chloro-3-(1-methoxy-1-methyl-ethoxy)-butane
133341-65-8, 133341-66-9

(S)-2-Chloro-3-(1-methoxy-1-methyl-ethoxy)-butane

Conditions
ConditionsYield
With oxalic acid In diethyl ether for 1h;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

4(S)-<(tert-butyloxycarbonyl)amino>-3-hydroxy-6-methyl-1-heptene
187532-13-4

4(S)-<(tert-butyloxycarbonyl)amino>-3-hydroxy-6-methyl-1-heptene

(4S)-3-(tert-butyloxycarbonyl)-2,2-dimethyl-5-ethenyl-4-(methylpropyl)oxazolidine
107599-96-2, 107616-02-4, 112190-34-8

(4S)-3-(tert-butyloxycarbonyl)-2,2-dimethyl-5-ethenyl-4-(methylpropyl)oxazolidine

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane for 4h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol
95791-07-4

(2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol

(4aR,6R,8aS)-6-Allyl-4,4a,6,8a-tetrahydro-2,2-dimethylpyrano<3,2-d>-m-dioxin
122490-43-1

(4aR,6R,8aS)-6-Allyl-4,4a,6,8a-tetrahydro-2,2-dimethylpyrano<3,2-d>-m-dioxin

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane 1.) 0 deg C, 2 h, 2.) 3 h;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

1-β-D-Ribofuranosyl-3-hydroxy-4-ethoxycarbonylpyranose
80744-51-0

1-β-D-Ribofuranosyl-3-hydroxy-4-ethoxycarbonylpyranose

1-(2,3-O-Isopropylidene-β-Dribofuranosyl)-3-hydroxy-4-ethoxycarbonylpyrazole
80755-76-6

1-(2,3-O-Isopropylidene-β-Dribofuranosyl)-3-hydroxy-4-ethoxycarbonylpyrazole

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; mercury dichloride In acetone at 20℃; for 3h;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

3β-acetoxy-17β-pivaloylandrost-5-ene-19-ol
67192-85-2

3β-acetoxy-17β-pivaloylandrost-5-ene-19-ol

2,2-Dimethyl-propionic acid (3S,8R,9S,10S,13S,14S,17S)-3-acetoxy-10-(1-methoxy-1-methyl-ethoxymethyl)-13-methyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl ester
98620-85-0

2,2-Dimethyl-propionic acid (3S,8R,9S,10S,13S,14S,17S)-3-acetoxy-10-(1-methoxy-1-methyl-ethoxymethyl)-13-methyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl ester

Conditions
ConditionsYield
With toluene-4-sulfonic acid In 1,4-dioxane100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(4S)-(-)-4,5-dihydroxy-3-methyl-2-butenoic acid 1,4-lactone
112837-18-0

(4S)-(-)-4,5-dihydroxy-3-methyl-2-butenoic acid 1,4-lactone

(4S)-(-)-4-hydroxy-5-<(2-methoxypropyl)oxy>-3-methyl-2-butenoic acid lactone
135006-19-8

(4S)-(-)-4-hydroxy-5-<(2-methoxypropyl)oxy>-3-methyl-2-butenoic acid lactone

Conditions
ConditionsYield
With trichlorophosphate for 6h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(9S)-9-dihydro-3,5-O-(p-methoxybenzylidene)erythronolide A
138505-32-5

(9S)-9-dihydro-3,5-O-(p-methoxybenzylidene)erythronolide A

(9S)-9-dihydro-9,11-O-isopropylidene-3,5-O-(p-methoxybenzylidene)erythronolide
138505-33-6

(9S)-9-dihydro-9,11-O-isopropylidene-3,5-O-(p-methoxybenzylidene)erythronolide

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane at 25℃; for 1.5h;100%
With pyridinium p-toluenesulfonate In dichloromethane at 25℃; for 1.5h;
2-Methoxypropene
116-11-0

2-Methoxypropene

(1α,2α,4β,5β)-diethyl N,N'-(4,5-dihydroxy-1,2-cyclohexanediyl)bis
135619-33-9

(1α,2α,4β,5β)-diethyl N,N'-(4,5-dihydroxy-1,2-cyclohexanediyl)bis

(3aα,5α,6α,7aα)-diethyl N,N'-(hexahydro-2,2-dimethyl-1,3-benzodioxole-5,6-diyl)bis
135619-23-7

(3aα,5α,6α,7aα)-diethyl N,N'-(hexahydro-2,2-dimethyl-1,3-benzodioxole-5,6-diyl)bis

Conditions
ConditionsYield
With toluene-4-sulfonic acid In acetone for 1h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

2-hydroxymethyl-4-phenylselenobutan-1-ol
102070-57-5

2-hydroxymethyl-4-phenylselenobutan-1-ol

2,2-dimethy-5-(2-phenylselenoethyl)-1,3-dioxane
90475-37-9

2,2-dimethy-5-(2-phenylselenoethyl)-1,3-dioxane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In dichloromethane for 1.5h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(1S,6R)-6-<(tert-butyldimethylsilyl)oxy>-1-<(1S,2S)-2-methyl-1,2,3-trihydroxypropyl>-5-methylene-7,9-diaza-2-oxabicyclo<4.2.2>decane-8,10-dione
95237-56-2

(1S,6R)-6-<(tert-butyldimethylsilyl)oxy>-1-<(1S,2S)-2-methyl-1,2,3-trihydroxypropyl>-5-methylene-7,9-diaza-2-oxabicyclo<4.2.2>decane-8,10-dione

(1S,6R)-6-<(tert-butyldimethylsilyl)oxy>-1-<(1S,2S)-2,3-O-isopropylidene-2-methyl-1,2,3-trihydroxypropyl>-5-methylene-7,9-diaza-2-oxabicyclo<4.2.2>decane-8,10-dione
95237-57-3

(1S,6R)-6-<(tert-butyldimethylsilyl)oxy>-1-<(1S,2S)-2,3-O-isopropylidene-2-methyl-1,2,3-trihydroxypropyl>-5-methylene-7,9-diaza-2-oxabicyclo<4.2.2>decane-8,10-dione

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In acetone for 12h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(Z)-(1R,9S,10R,12S)-10,12-Bis-(tert-butyl-dimethyl-silanyloxy)-13-oxa-bicyclo[7.3.1]tridec-7-ene-4,5-diol

(Z)-(1R,9S,10R,12S)-10,12-Bis-(tert-butyl-dimethyl-silanyloxy)-13-oxa-bicyclo[7.3.1]tridec-7-ene-4,5-diol

(Z)-(1R,12S,13R,15S)-13,15-Bis-(tert-butyl-dimethyl-silanyloxy)-6,6-dimethyl-5,7,16-trioxa-tricyclo[10.3.1.04,8]hexadec-10-ene
143109-21-1

(Z)-(1R,12S,13R,15S)-13,15-Bis-(tert-butyl-dimethyl-silanyloxy)-6,6-dimethyl-5,7,16-trioxa-tricyclo[10.3.1.04,8]hexadec-10-ene

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane at 0℃; for 3h;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

<1S-<1α(4R*,5R*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-<4-(acetyloxy)-5-methyl-3-methylene-6-phenylhexyl>4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester
144358-24-7

<1S-<1α(4R*,5R*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-<4-(acetyloxy)-5-methyl-3-methylene-6-phenylhexyl>4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester

(1S,3S,4S,5R,6R,7R)-1-((4S,5R)-4-Acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-4-hydroxy-7-(1-methoxy-1-methyl-ethoxy)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester
146008-36-8

(1S,3S,4S,5R,6R,7R)-1-((4S,5R)-4-Acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-4-hydroxy-7-(1-methoxy-1-methyl-ethoxy)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane for 2h; Ambient temperature;100%
With pyridinium p-toluenesulfonate In dichloromethane at 0℃; for 2h;95%
2-Methoxypropene
116-11-0

2-Methoxypropene

(1S,2S,3S)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol
144242-33-1

(1S,2S,3S)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

(1S,2S,3S)-1-(phenylthio)-2,3-O-isopropylidene-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol
144242-34-2

(1S,2S,3S)-1-(phenylthio)-2,3-O-isopropylidene-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane for 3.5h;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol
144301-64-4

(1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

(1R,2R,3R)-1-(phenylthio)-2,3-O-isopropylidene-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

(1R,2R,3R)-1-(phenylthio)-2,3-O-isopropylidene-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane for 3.5h;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(2S,3S)-3-benzenethio-3-(trimethylosilyl)propane-1,2-diol
150841-73-9

(2S,3S)-3-benzenethio-3-(trimethylosilyl)propane-1,2-diol

(2S,3S)-3-benzenethio-1,2-O-isopropylidene-3-(trimethylsilyl)propane-1,2-diol
150841-74-0

(2S,3S)-3-benzenethio-1,2-O-isopropylidene-3-(trimethylsilyl)propane-1,2-diol

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane for 1.5h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

(1R,2S,1'S,2'S)-2-(2'-tert-butoxycarbonylamino-1'-hydroxy-3'-phenylpropyl)cyclopentane-1-carboxylic acid n-butylamide
153077-97-5

(1R,2S,1'S,2'S)-2-(2'-tert-butoxycarbonylamino-1'-hydroxy-3'-phenylpropyl)cyclopentane-1-carboxylic acid n-butylamide

(4S,5S,1'S,2'R)-4-benzyl-3-N-tert-butoxycarbonyl-5-(2'-n-butylaminocarbonyl)cyclopentyl-2,2-dimethyloxazolidine
155186-38-2

(4S,5S,1'S,2'R)-4-benzyl-3-N-tert-butoxycarbonyl-5-(2'-n-butylaminocarbonyl)cyclopentyl-2,2-dimethyloxazolidine

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane for 1.5h; Ambient temperature;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

C34H58O9Si2
153145-23-4

C34H58O9Si2

C38H66O10Si2
153145-24-5

C38H66O10Si2

Conditions
ConditionsYield
With toluene-4-sulfonic acid100%
2-Methoxypropene
116-11-0

2-Methoxypropene

benzaldehyde
100-52-7

benzaldehyde

[3-Methoxy-1-(1-methoxy-1-methyl-ethoxy)-but-3-enyl]-benzene
148587-25-1

[3-Methoxy-1-(1-methoxy-1-methyl-ethoxy)-but-3-enyl]-benzene

Conditions
ConditionsYield
With tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; silica gel; acetic acid at 25℃;100%
With silica gel; acetic acid; tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium In dichloromethane at 25℃; Addition;100%
2-Methoxypropene
116-11-0

2-Methoxypropene

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

4-Hydroxy-2-((Z)-8-hydroxy-7-oxo-oct-2-enyl)-cyclopent-2-enone

4-Hydroxy-2-((Z)-8-hydroxy-7-oxo-oct-2-enyl)-cyclopent-2-enone

2-[(Z)-6-(4-Methoxy-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enyl]-4-(1-methoxy-1-methyl-ethoxy)-cyclopent-2-enone

2-[(Z)-6-(4-Methoxy-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enyl]-4-(1-methoxy-1-methyl-ethoxy)-cyclopent-2-enone

Conditions
ConditionsYield
With toluene-4-sulfonic acid100%
2-Methoxypropene
116-11-0

2-Methoxypropene

2-nitro-benzaldehyde
552-89-6

2-nitro-benzaldehyde

1-[3-Methoxy-1-(1-methoxy-1-methyl-ethoxy)-but-3-enyl]-2-nitro-benzene

1-[3-Methoxy-1-(1-methoxy-1-methyl-ethoxy)-but-3-enyl]-2-nitro-benzene

Conditions
ConditionsYield
With tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; silica gel; acetic acid at 25℃;100%
With silica gel; acetic acid; tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium In dichloromethane at 25℃; Addition;99%
2-Methoxypropene
116-11-0

2-Methoxypropene

5,6-anhydro-1,2-O-isopropylidene-α-D-glucofuranose
15354-69-5

5,6-anhydro-1,2-O-isopropylidene-α-D-glucofuranose

5,6-anhydro-1,2-O-isopropylidene-3-O-(1-methoxy-1-methyl ethyl)-α-D-glucofuranose
86949-76-0

5,6-anhydro-1,2-O-isopropylidene-3-O-(1-methoxy-1-methyl ethyl)-α-D-glucofuranose

Conditions
ConditionsYield
With trifluoroacetic acid In chloroform100%
With trifluoroacetic acid In dichloromethane for 4h; Ambient temperature;673 mg
2-Methoxypropene
116-11-0

2-Methoxypropene

(S)-Methyl mandelate
21210-43-5

(S)-Methyl mandelate

(S)-(1-Methoxy-1-methyl-ethoxy)-phenyl-acetic acid methyl ester
167702-78-5

(S)-(1-Methoxy-1-methyl-ethoxy)-phenyl-acetic acid methyl ester

Conditions
ConditionsYield
With dichloro-acetic acid at 20℃; for 60h;100%

116-11-0Related news

Reaction sof d-lyxose and d-xylose with 2-Methoxypropene (cas 116-11-0) under kinetic conditions☆08/24/2019

d-Lyxose (1) undergoes acetonation under kinetic conditions with 2-methoxypropene to give 2,3-O-isopropylidene-α-d-lyxofuranose (2) in high yield, further characterized as its 1,5-diacetate 3, thus affording a preparative route to 2. Forcing conditions are required to bring d-xylose (5) into re...detailed

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