118249-11-9

Upstream product

• 14804-38-7 5-bromo-2-methoxy-1,3-dimethylbenzene 
• 6296-63-5 4-bromo-2,6-bis(hydroxymethyl)phenol 
• 2374-05-2 4-bromo-2,6-dimethyl-phenol 
• 106-41-2 4-bromo-phenol 
• 89479-09-4 [5-bromo-3-(hydroxymethyl)-2-methoxyphenyl]methanol 

Downstream Products

• 189451-78-3 (4S,14S)-19-Bromo-21-methoxy-4,14-diphenyl-3,6,9,12,15-pentaoxa-bicyclo[15.3.1]henicosa-1⁽²⁰⁾,17⁽²¹⁾,18-triene 
• 379668-71-0 2,6-bis[2-(o-nitrophenoxy)methyl]-4-bromo-1-methoxybenzene 
• 497107-20-7 5-bromo-1,3-bis[(4S)-4-hydroxy-4-phenyl-2-oxobutyl]-2-methoxybenzene 
• 848360-65-6 5-bromo-2-methoxy-1,3-bis(phenoxymethyl)benzene 
• 946533-32-0 C₂₅H₂₉BrN₂O₁₂ 
• 848360-66-7 4-methoxy-3,5-bis(phenoxymethyl)phenol 
• 1204655-00-4 2,6-bis(sulfanylmethyl)-4-bromoanisole 
• 1262519-64-1 2,6-bis[(N-tert-butyloxycarbonyl)aminomethyl]-4-(4',4',5',5'-tetramethyl-1',3',2'-dioxaborolan-2'-yl)anisole 
• 1380485-23-3 4-bromo-2,6-bis(azidomethyl)anisole 
• 89479-20-9 4-bromo-2,6-bis(aminomethyl)anisole 
• 1380485-32-4 2,6-bis[(N-tert-butyloxycarbonyl)aminomethyl]-4-bromoanisole 
• 1380485-34-6 3,5-bis[(N-tert-butyloxycarbonyl)aminomethyl]-4-[4'-(4'',4'',5'',5''-tetramethyl-1'',3'',2''-dioxaborolan-2''-yl)phenyl]anisole 
• 946533-36-4 C₂₉H₃₇BrN₂O₁₄ 
• 946533-34-2 C₂₇H₃₃BrN₂O₁₃ 

Relevant academic research and scientific papers

High-affinity disaccharide binding by tricyclic synthetic lectins

Stay flexible: Rigid preorganization is not always the best approach to molecular recognition. Unlike previous synthetic lectins, new receptors (see picture) were synthesized that possess conformational freedom which allows hydrophobically driven collapse

CHIRAL SENSOR

An optically active compound having an unsaturated bond at an optically active binding site, wherein the unsaturated bond and a fluorescent substituent or a substituent capable of imparting fluorescence are united in a conjugated manner; and a chiral sens

Phenol-containing macrocyclic diamides as new catalysts in the highly regioselective conversion of epoxides to β-hydroxy thiocyanates

The regioselective ring-opening reactions of some epoxides with ammonium thiocyanate in the presence of a series of new phenol-containing macrocyclic diamides and also dibenzo-18-crown-6-, 18-crown-6-, benzo-15-crown-5-, and pyridine-containing macrocyclic diamide have been studied. The epoxides were subject to cleavage by NH4SCN in the presence of these catalysts under mild reaction conditions in various aprotic solvents. In this study, reagents and conditions have been discovered with which the individual β-hydroxy thiocyanates can be synthesized in high yield and with more than 90% regioselectivity. The results can be discussed in terms of a four-step mechanism: (1) formation of complex between catalyst and NH4SCN, (2) release of SCN- nucleophile from the complex, (3) reaction of the active nucleophile at the less sterically hindered site in the epoxide, and (4) regeneration of catalyst. The major advantages of this method are as follows: (1) high regioselectivity, (2) simple regeneration of catalyst, (3) its reuse through several cycles without a decrease in activity, and (4) ease of workup of the reaction.

Metacyclophanes and Related Compounds. 21. Nitration of Metacyclophanes

Various metacyclophanes were prepared from the corresponding benzene derivatives by using the tert-butyl group as a positional protective function and their nitrations were carried out under various conditions.It was found that nitration of 8,16-dime

SYNTHETIC MACROCYCLIC LIGANDS. VI. LITHIUM ION-SELECTIVE FLUORESCENT EMISSION WITH CROWNED BENZO- AND NAPHTO-THIAZOLYLPHENOLS

Synthesis of fluorescent crowned benzo- and naphto-thiazolylphenols are described and lithium ion-selective fluorescent emission is observed under the restricted conditions.