118251-80-2Relevant academic research and scientific papers
Iridium-catalysed Homogeneous Hydrogenation of Prochiral Enamides Containing Tetrasubstituted Alkene Moieties
Oro, Luis A.,Cabeza, Javier A.,Cativiela, Carlos,Villegas, Maria D. Diaz de,Melendez, Enrique
, p. 1383 - 1384 (1983)
The tetrasubstituted prochiral amido-alkenes (1a, b), (2a, b), and (3b) have been homogeneously hydrogenated under very mild conditions by iridium complexes of the type (cod = cyclo-octa-1,5-diene, bzn = benzonitrile, L = tricycloh
Homogeneous Hydrogenation of Tetrasubstituted Alkene Moieties in Prochiral Didehydro Amino Acid Derivatives Catalysed by Iridium Complexes
Cabeza, Javier A.,Cativiela, Carlos,de Villegas, Maria D. Diaz,Oro, Luis A.
, p. 1881 - 1884 (2007/10/02)
The hydrogenation of the tetrasubstituted alkene moieties of prochiral didehydro amino acid derivatives (1a and b), (2a and b), (3b), (+) and (-)-(6), (+)-(7), and (-)-(9) has been succesfully achieved under very mild homogeneous conditions (1 atm of H2;
