118356-16-4Relevant articles and documents
Simple synthesis of β-acetoxy thiocyanates from oxiranes
Lukowska-Chojnacka, Edyta,Plenkiewicz, Jan
, p. 1999 - 2006 (2011/06/24)
A convenient and simple method for the preparation of previously unknown β-acetoxy thiocyanates by regioselective ring opening of the corresponding oxiranes with thiocyanate anion followed by acetylation is described. The shorter reaction times, better yields of the products, and easy workup are the advantages of this methodology.
Substituted Lithium (E)-3-Lithio-3-tosyl-2-propenolates: Useful Intermediates in Organic Synthesis
Najera, Carmen,Yus, Miguel
, p. 1491 - 1499 (2007/10/02)
The lithiation of substituted tosylated epoxides 7 derived from allylic sulfones with methyllithium leads to lithium (E)-3-lithio-3-tosyl-2-propenolates 5 in a stereoselective manner.The further reaction of these intermediates with different electrophilic