118356-53-9Relevant academic research and scientific papers
Substituted Lithium (E)-3-Lithio-3-tosyl-2-propenolates: Useful Intermediates in Organic Synthesis
Najera, Carmen,Yus, Miguel
, p. 1491 - 1499 (2007/10/02)
The lithiation of substituted tosylated epoxides 7 derived from allylic sulfones with methyllithium leads to lithium (E)-3-lithio-3-tosyl-2-propenolates 5 in a stereoselective manner.The further reaction of these intermediates with different electrophilic
A 1,3-Rearrangement of Allylic Sulphones Caused by m-Chloroperbenzoic Acid and Sodium Hydrogen Carbonate
Kocienski, Philip
, p. 945 - 948 (2007/10/02)
The reaction of allylic sulphones with m-chloroperbenzoic acid in the presence of aqueous sodium hydrogen carbonate can result in 1,3-allylic rearrangement or isomerisation of the double bond depending on the structure of the allylic sulphone.Subsequent e
