1184-42-5

Basic information

• Product Name: 2,2,4,4,6,6-hexakis(4-methoxyphenoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine
• CAS NO: 1184-42-5
• Molecular Formula: C₄₂H₄₂N₃O₁₂P₃
• Molecular Weight: 873.7171
• Mol File: 1184-42-5.mol
• Article Data: 6

Chemical Properties

• Density: 1.33g/cm³
• Refractive Index: 1.598
• CAS DataBase Reference: 2,2,4,4,6,6-hexakis(4-methoxyphenoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,4,4,6,6-hexakis(4-methoxyphenoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine(1184-42-5)
• EPA Substance Registry System: 2,2,4,4,6,6-hexakis(4-methoxyphenoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine(1184-42-5)

Safety Data

• Hazardous Substances Data: 1184-42-5(Hazardous Substances Data)

Usage

Molecular structure

A triazatriphosphinine ring with six 4-methoxyphenoxy groups attached

Symmetry

Highly symmetrical with six identical substituents

Trivalent phosphorus atom

The compound contains a trivalent phosphorus atom

Potential applications

Coordination chemistry, catalysis, materials science

Unique molecular structure

The compound has a unique molecular structure due to its triazatriphosphinine ring and six identical substituents

Phosphorus content

The presence of phosphorus makes it potentially useful in the development of new phosphine ligands

Steric and electronic effects

The methoxy groups provide steric and electronic effects, making the compound interesting for further study and potential application in various chemical reactions.

Upstream product

• 150-76-5 4-methoxy-phenol 
• 940-71-6 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine 

Downstream Products

• 134177-58-5 N3P3(OC6H4OCH3)5{(η6-OC6H4OCH3)Cr(CO)3} 
• 23788-22-9 2,2,4,4,6,6-hexakis(4-hydroxyphenoxy)cyclotriphosphazatriene 

Relevant articles and documents

Cobaltabisdicarbollide based metallodendrimers with cyclotriphosphazene core

Cyclotriphosphazene core based metallodendrimers containing six and twelve cobalt bis(dicarbollide) moieties on the periphery have been synthesized. The ring opening reaction of the cyclic oxonium derivative of the cobalt bis(dicarbollide) anion, [3,3′-Co

METHOD FOR PRODUCING CYCLIC ARYLOXYPHOSPHAZENE

PROBLEM TO BE SOLVED: To provide a method for producing a cyclic aryloxyphosphazene in a short time and in high yield under a mild condition by a simple operation. SOLUTION: Provided is a method for producing a cyclic aryloxyphosphazene represented by Formula (2), comprising reacting hexachlorocyclotriphosphazene with an aryl alcohol in a nitrile only or an organic solvent mixed with 40 vol.% or more and less than 100 vol.% of a nitrile in the presence of a pellet-like material of al least one hydroxide selected from the group consisting of potassium hydroxide and sodium hydroxide. [Ar is a substituted or unsubstituted aryl group.] SELECTED DRAWING: None COPYRIGHT: (C)2020,JPO&INPIT

A novel synthesis of hexasubstituted cyclotriphosphazenes

Hexaaryloxyphosphazenes [N3P3(O-C6H4-R)6] (R=H, CH3, OCH3, C(CH3)3, CHO, COCH3, COOR, C6H5, NO2, F, etc) were readily obtained with ca 70% isolated yield in refluxing acetonitrile in the presence of anhydrous potassium phosphate. All compounds were characterized by means of elemental analysis, 1H-NMR, 31P-NMR spectroscopy.