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Hexachlorocyclotriphosphazene 99.5%
Cas No: 940-71-6
No Data 25 Kilogram 50 Metric Ton/Month Zibo Kunran Enterprises Co. LTD Contact Supplier
Phosphonitrilic chloride trimer
Cas No: 940-71-6
No Data 1 Gram 10 Metric Ton/Day Hangzhou KieRay Chem Co.,Ltd. Contact Supplier
Phosphonitrilic chloride trimer
Cas No: 940-71-6
No Data 25 Kilogram 60 Metric Ton/Month Qingdao Kaimosi Biochemical Technology Co.,Ltd. Contact Supplier
Phosphonitrilic chloride trimer Manufacturer/High quality/Best price/In stock
Cas No: 940-71-6
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High purity 940-71-6 HEXACHLOROCYCLOTRIPHOSPHAZENE
Cas No: 940-71-6
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Phosphonitrilic chloride trimer
Cas No: 940-71-6
USD $ 10.0-15.0 / Kilogram 1 Kilogram 500 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier
Amadis Chemical offer CAS#940-71-6;CAT#A844800
Cas No: 940-71-6
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Phosphonitrile chloride cyclic trimer
Cas No: 940-71-6
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Factory Supply Hexachlorocyclo triphosphonitrile
Cas No: 940-71-6
No Data 1 Kilogram 400 Metric Ton/Day Ality Chemical Corporation Contact Supplier
940-71-6
Cas No: 940-71-6
No Data 1 Kilogram 1000 Kilogram/Week Henan Tianfu Chemical Co., Ltd. Contact Supplier

940-71-6 Usage

Chemical Properties

white crystalline powder

Purification Methods

Purify it by zone melting, by crystallisation from pet.ether, n-hexane or *benzene, and by sublimation. [van der Huizen et al. J Chem Soc, Dalton Trans 1311 1986, Meirovitch et al. J Phys Chem 88 1522 1984, Alcock et al. J Am Chem Soc 106 5561 1984; Winter & van de Grampel J Chem Soc, Dalton Trans 1269 1986.] Phosphoric acid [7664 -38 -2] M 98.0, m 42.3o, pK 1 2.15, pK 2 7.21, pK 3 12.37. Pyrophosphate can be removed from phosphoric acid by diluting with distilled H2O and refluxing overnight. By cooling to 11o and seeding with crystals obtained by cooling a few millilitres in a Dry-ice/acetone bath, 85% orthophosphoric acid crystallises as H3PO4.H2O. The crystals are collected on a sintered glass filter. [Weber & King Inorg Synth I 101 1939.]
InChI:InChI=1/Cl6N3P3/c1-10(2)7-11(3,4)9-12(5,6)8-10

940-71-6 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (481947)  Phosphonitrilicchloridetrimer  99.95% trace metals basis 940-71-6 481947-25G 2,788.11CNY Detail
Aldrich (481947)  Phosphonitrilicchloridetrimer  99.95% trace metals basis 940-71-6 481947-5G 806.13CNY Detail
Alfa Aesar (A18986)  Phosphonitrilic chloride trimer, 98%    940-71-6 100g 1546.0CNY Detail
Alfa Aesar (A18986)  Phosphonitrilic chloride trimer, 98%    940-71-6 25g 517.0CNY Detail
Alfa Aesar (A18986)  Phosphonitrilic chloride trimer, 98%    940-71-6 5g 159.0CNY Detail

940-71-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Phosphonitrilic chloride trimer

1.2 Other means of identification

Product number -
Other names 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2λ<sup>5</sup>,4λ<sup>5</sup>,6λ<sup>5</sup>-triphosphacyclohexa-1,3,5-triene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:940-71-6 SDS

940-71-6Synthetic route

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride
12125-02-9

ammonium chloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
With pyridine; magnesium chloride In chlorobenzene at 80 - 132℃; Inert atmosphere;71%
Stage #1: ammonium chloride With pyridine; magnesium chloride In 1,1,2,2-tetrachloroethane at 145℃; for 12h;
Stage #2: phosphorus pentachloride In 1,1,2,2-tetrachloroethane at 145℃; Solvent; Temperature;
61.78%
In chlorobenzene at 120 - 130℃; Inert atmosphere; Reflux;60.6%
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride
12125-02-9

ammonium chloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

(NPCl2)8
14514-98-8

(NPCl2)8

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

D

Cl18N9P9

Cl18N9P9

E

pentakisphosphorus nitride dichloride
13596-41-3

pentakisphosphorus nitride dichloride

F

hexakisphosphorus nitride dichloride
2851-52-7

hexakisphosphorus nitride dichloride

G

heptakisphosphorus nitride dichloride
13827-30-0

heptakisphosphorus nitride dichloride

Conditions
ConditionsYield
In chlorobenzene Schlenk technique; Reflux;A 64%
B 6%
C 5%
D 2%
E 16%
F 16%
G 13%
tris(trimethylsilyl)amine
1586-73-8

tris(trimethylsilyl)amine

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In dichloromethane inert atmosphere; dropwise addn. of 1 equiv. PCl5 to amine at 25°C, stirring for 12 h; not isolated, detd. by (31)P-NMR spectroscopy;49%
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride

ammonium chloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In chlorobenzene react. of PCl5 with NH4Cl (ratio 1:1.5) in C6H5Cl at 124-127 °C (20-50 h);;40%
In chlorobenzene react. of PCl5 with NH4Cl (ratio 1:1.2) in C6H5Cl at 132-134 °C (20 h);;20-22
In further solvent(s) in 1,1,2,2-tetrachloroethane; recrystn. from petroleum ether;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonia
7664-41-7

ammonia

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In further solvent(s) passing gaseous NH3 in a soln. of PCl5 in (CHCl2)2;;16%
tris(trimethylsilyl)amine
1586-73-8

tris(trimethylsilyl)amine

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

trichloro(trimethylsilyl)phosphoranimine
40678-60-2

trichloro(trimethylsilyl)phosphoranimine

Conditions
ConditionsYield
In dichloromethane inert atmosphere; dropwise addn. of 0.5-1 equiv. PCl5 to amine at -78 or25°C, stirring for 30 min to 12 h; yields depending on educt rat io, reaction temp., time and rate of addn.; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;A 5%
B 5%
thionyl chloride
7719-09-7

thionyl chloride

tetrasulfur tetranitride
28950-34-7

tetrasulfur tetranitride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In benzene addn. of PCl3 to a soln. of S4N4 in C6H6 containing SOCl2; formation of a brown main product and crystals of (PNCl2)3;;
In benzene addn. of PCl3 to a soln. of S4N4 in C6H6 containing SOCl2; formation of a brown main product and crystals of (PNCl2)3;;
mercury amidochloride
10124-48-8

mercury amidochloride

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

phosphorus chloride nitride

phosphorus chloride nitride

C

ammonium chloride

ammonium chloride

D

mercury dichloride

mercury dichloride

Conditions
ConditionsYield
In neat (no solvent) heating with HgNH2Cl; formation of a mixture of P3N3Cl6, (PNCl2)(n), HgCl2 and NH4Cl;;
In neat (no solvent) heating with HgNH2Cl; formation of a mixture of P3N3Cl6, (PNCl2)(n), HgCl2 and NH4Cl;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonia
7664-41-7

ammonia

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

C

ammonium chloride

ammonium chloride

Conditions
ConditionsYield
In tetrachloromethane pptn. of NH4Cl from a soln. of 3 g PCl5 in 1000 ml CCl4 half-saturated with gaseous NH3 at -3 °C; soln. contains (PNCl2)3 and (PNCl2)4;; evapn. of the mother liquor, fractional crystn. from toluene;;
In tetrachloromethane pptn. of NH4Cl from a soln. of 3 g PCl5 in 1000 ml CCl4 half-saturated with gaseous NH3 at -3 °C; soln. contains (PNCl2)3 and (PNCl2)4;; evapn. of the mother liquor, fractional crystn. from toluene;;
ammonium chloride

ammonium chloride

chlorine
7782-50-5

chlorine

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In further solvent(s) dissolving PCl3 distd. under N2 in benzyl chloride distd. under N2; addn. of NH4Cl dryed in vac. and passing in the corresponding amount of Cl2; heating in a stream of N2 at 130 °C; removal of formed HCl by a stream of N2;; filtration, distg. off the solvent at 40 °C and 0.5 Torr; recrystn. from petroleum ether; product contains small amounts of higher polymers;;
ammonium chloride

ammonium chloride

chlorine
7782-50-5

chlorine

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

C

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

D

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In further solvent(s) dissolving PCl3 distd. under N2 in (CHCl2)2 distd. under N2; addn. of NH4Cl dryed in vac. and passing in the corresponding amount of Cl2; heating in a stream of N2 at 130 °C; removal of formed HCl by a stream of N2;; filtration, distg. off the solvent at 40 °C and 0.5 Torr; recrystn. from petroleum ether; products (NPCl2)3, (NPCl2)4 and a small amount of oily polymers;;
In chlorobenzene dissolving PCl3 distd. under N2 in C6H5Cl distd. under N2; addn. of NH4Cl dryed in vac. and passing in the corresponding amount of Cl2; heating in a stream of N2 at 130 °C; removal of formed HCl by a stream of N2;; filtration, distg. off the solvent at 40 °C and 0.5 Torr; recrystn. from petroleum ether; product contains small amounts of higher polymers;;
In further solvent(s) dissolving PCl3 distd. under N2 in (CHCl2)2 distd. under N2; addn. of NH4Cl dryed in vac. and passing in the corresponding amount of Cl2; heating in a stream of N2 at 130 °C; removal of formed HCl by a stream of N2;; filtration, distg. off the solvent at 40 °C and 0.5 Torr; recrystn. from petroleum ether; yield 35-40 %, product contains small amounts of higher polymers;;A n/a
B 35-40
C n/a
D n/a
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride

ammonium chloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In not given react. of 400 g PCl5 with 120 g NH4Cl in an inert solvent;; sucking off the formed mass, washing with ice-cold C6H6; fractional distn.; yield 50 % (NPCl2)3, 25 % (NPCl2)4 and 25 % higher polymers;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride

ammonium chloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In not given react. of 400 g PCl5 with 120 g NH4Cl in an inert solvent;; sucking off the formed mass, washing with ice-cold C6H6; fractional distn.; yield 75 g (NPCl2)3, 25 g (NPCl2)4;;
In not given react. of PCl5 with NH4Cl;; fractionation at 185-190 °C and 13 Torr; fraction contains 10 % (NPCl2)3;;
In not given react. of PCl5 with NH4Cl;; fractionation at 185-190 °C and 13 Torr; fraction contains 10 % (NPCl2)3;;
In further solvent(s) react. of finely divided NH4Cl and PCl5 in refluxing sym-tetrachloroethane; fractional crystn. from glacial acetic acid, cold benzene and conc. H2SO4;
phosphorus(V) nitride

phosphorus(V) nitride

chlorine
7782-50-5

chlorine

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

D

nitrogen
7727-37-9

nitrogen

Conditions
ConditionsYield
In neat (no solvent) formation of a mixt. of phosphorus nitride dichlorides with a large amount of (NPCl2)3 and a small amount of PCl5 by react. of P3N5 with Cl2 at 700 °C;;
sodium azide

sodium azide

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In nitrobenzene small amount of azide; detected by NMR;
lithium azide
19597-69-4

lithium azide

trichloro(o-phenylenedioxy)phosphorane
2007-97-8

trichloro(o-phenylenedioxy)phosphorane

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

hexaazido cyclotriphosphazene
22295-99-4

hexaazido cyclotriphosphazene

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In nitrobenzene not isolated, detected by NMR;
2,4-dichloro-1,3-bis(dichlorophosphoryl)-2,4-dioxocyclodiphosph(V)azane
64373-45-1

2,4-dichloro-1,3-bis(dichlorophosphoryl)-2,4-dioxocyclodiphosph(V)azane

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

dichlorophosphinylphosphorimidic trichloride
13966-08-0

dichlorophosphinylphosphorimidic trichloride

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In trichlorophosphate byproducts: Cl2(O)P(NPCl2)5Cl; under reflux; treatment of the crude product with n-heptane, products identified in the sol. and in the insol. phase with NMR spectroscopy;
P4N6

P4N6

chlorine
7782-50-5

chlorine

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

D

nitrogen
7727-37-9

nitrogen

Conditions
ConditionsYield
In neat (no solvent) formation of a mixt. of phosphorus nitride dichlorides with a large amount of (NPCl2)3 and a small amount of PCl5 by react. of P4N6 with Cl2 at 700 °C;;
thionyl chloride
7719-09-7

thionyl chloride

tetrasulfur tetranitride
28950-34-7

tetrasulfur tetranitride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

Conditions
ConditionsYield
In benzene formation of phosphorus nitride dichlorides with a large amount of (NPCl2)3 as by-products by addn. of PCl3 to a soln. of S4N4 in C6H6 containing SOCl2;;
In benzene
phospham

phospham

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
With hydrogenchloride In further solvent(s) passing dry gaseous HCl into a suspension of phospham in 1.1.2.2-tetrachlorethane at 148°C for several h;;
phosphorus(V) chloride * 8 NH3

phosphorus(V) chloride * 8 NH3

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

Conditions
ConditionsYield
In neat (no solvent) formation of phosphorus nitride dichlorides with a large amount of (NPCl2)3 on heating PCl5*8NH3 at 175-200 °C and 50 Torr;;
phosphorus(V) chloride * 8 NH3

phosphorus(V) chloride * 8 NH3

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
In neat (no solvent) sublimation of (PNCl2)3 at 175-200 °C and 50 Torr;;
In neat (no solvent) sublimation of (PNCl2)3 at 175-200 °C and 50 Torr;;
Mg2PN3

Mg2PN3

chlorine
7782-50-5

chlorine

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

nitrogen
7727-37-9

nitrogen

D

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In neat (no solvent) formation of phosphorus nitride dichlorides with a large amount of (NPCl2)3 on heating PN3Mg2 in a stream of Cl2 at 700 °C;;
{Cl(Cl2PN)3PCl3}(1+)*{BCl4}(1-)={Cl(Cl2PN)3PCl3}{BCl4}
21246-65-1

{Cl(Cl2PN)3PCl3}(1+)*{BCl4}(1-)={Cl(Cl2PN)3PCl3}{BCl4}

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

{PCl4}(1+)*{BCl4}(1-)={PCl4}{BCl4}
18460-54-3

{PCl4}(1+)*{BCl4}(1-)={PCl4}{BCl4}

Conditions
ConditionsYield
130°C;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

heptakisphosphorus nitride dichloride
13827-30-0

heptakisphosphorus nitride dichloride

Conditions
ConditionsYield
With quinoline In further solvent(s) heating a soln. of PCl5 in (CHCl2)2 with quinoline at 145 °C on refluxing;; distn. off solvent; formation of a mixt. of 40 % (NPCl2)3, 55-60 % (PNCl2)7 and 0-5 % impurities;;
With quinoline
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

C

dichlorophosphinylphosphorimidic trichloride
13966-08-0

dichlorophosphinylphosphorimidic trichloride

Conditions
ConditionsYield
In further solvent(s) react. of a soln. in tetrachlorethane with PCl5; immediate removal of HCl on passing thruogh a stream of air;;
In further solvent(s) react. of a soln. in tetrachlorethane with PCl5; immediate removal of HCl on passing thruogh a stream of air;;
tris(trimethylsilyl)amine
1586-73-8

tris(trimethylsilyl)amine

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

C

pentakisphosphorus nitride dichloride
13596-41-3

pentakisphosphorus nitride dichloride

D

hexakisphosphorus nitride dichloride
2851-52-7

hexakisphosphorus nitride dichloride

Conditions
ConditionsYield
In dichloromethane byproducts: high oligomers; inert atmosphere; dropwise addn. of 1 equiv. PCl5 to amine at reflux, refluxing for 8 h; distn.; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonia
7664-41-7

ammonia

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In tetrachloromethane incomplete satn. of a soln. of PCl5 in CCl4 with gaseous NH3;;
In tetrachloromethane
lithium azide
19597-69-4

lithium azide

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In nitrobenzene small amount of azide; detected by NMR;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hydrogen fluoride
7664-39-3

hydrogen fluoride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

ammonium hexafluorophosphate

ammonium hexafluorophosphate

Conditions
ConditionsYield
In not given react. with HF;;A n/a
B 100%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

sodium fluoride

sodium fluoride

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With 1-butyl-3-methylimidazolium Tetrafluoroborate In N,N-dimethyl-formamide at 50℃; for 5h; Reagent/catalyst; Solvent; Temperature;99.8%
With H2O or HF In nitrobenzene dissolving (NPCl2)3 in freshly distd. C6H5NO2; addn. of an excess of NaF or a small amount of H2O or HF under exclusion of H2O (drying tube with P2O5); heating on refluxing;; fractionation;;
In gas byproducts: NaCl; (NPCl2)3 gas was passed over heated NaF at 550°C; monitoring by IR spectroscopy;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

potassium thioacyanate
333-20-0

potassium thioacyanate

A

hexaisothiocyanatocyclotriphosphazene
1858-42-0

hexaisothiocyanatocyclotriphosphazene

B

potassium chloride

potassium chloride

Conditions
ConditionsYield
In acetoneA n/a
B 99%
In acetoneA n/a
B 99%
potassium fluoride

potassium fluoride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With 4-n-butyl-4-methylmorpholinium hydroxide In acetonitrile at 30℃; for 2h; Temperature; Solvent; Reagent/catalyst; Ionic liquid;98.7%
Reflux;90%
With catalyst: 18-crown-6 In tetrahydrofuran refluxing KF with catalytic amt. of crown for 20 min, dropwise addn. of 0.1 equiv. of N3P3Cl6, refluxing (1 h); fractional distn.;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

4-bromo-phenol
106-41-2

4-bromo-phenol

hexakis(4-bromophenoxy)cyclotriphosphazene
4376-72-1

hexakis(4-bromophenoxy)cyclotriphosphazene

Conditions
ConditionsYield
With potassium carbonate In acetone for 18h; Inert atmosphere; Reflux;98%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With potassium fluoride; Triethylene glycol dimethyl ether; ethanol In hexane at 0 - 30℃; for 2h; Solvent; Reagent/catalyst; Temperature;97.2%
With sodium fluoride In diethylene glycol dimethyl ether at 100℃; for 2h; Temperature; Solvent; Inert atmosphere;86%
In not given (N2); as in: (Schmutzler, R. Inorg Synth. 1967, 9, 75); fractional distn.;
With sodium fluoride In ethyl acetate at 10℃; for 3h; Solvent; Temperature; Reflux;130 g
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

isobutylamine
78-81-9

isobutylamine

hexakis(iso-butylamino) cyclotriphosphazene
101201-65-4

hexakis(iso-butylamino) cyclotriphosphazene

Conditions
ConditionsYield
In toluene for 24h; Reflux;97%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2,2'-dihydroxybiphenyl
1806-29-7

2,2'-dihydroxybiphenyl

2,2-dichloro-4,4,6,6-bis[spiro(2',2''-dioxy-1'',1''-biphenyl)]cyclotriphosphazene
128175-80-4

2,2-dichloro-4,4,6,6-bis[spiro(2',2''-dioxy-1'',1''-biphenyl)]cyclotriphosphazene

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran at 65℃; for 12h; Inert atmosphere;95.4%
With potassium carbonate In acetone at 0 - 20℃; for 24h; Inert atmosphere;92%
With potassium carbonate In acetone at 0 - 20℃; for 24h; Inert atmosphere;92%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

phenol
108-95-2

phenol

2,2,4,4,6,6-hexaphenoxycyclotriphosphazene
1184-10-7

2,2,4,4,6,6-hexaphenoxycyclotriphosphazene

Conditions
ConditionsYield
Stage #1: phenol With tetrabutylammomium bromide; chlorobenzene; potassium hydroxide at 50℃; for 0.5h;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine at 90℃; for 9h; Reagent/catalyst; Temperature;
95.04%
Stage #1: phenol With sodium hydride In tetrahydrofuran Inert atmosphere;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In tetrahydrofuran at 70℃; Inert atmosphere;
85%
With potassium carbonate In tetrahydrofuran at 50℃; for 24h;85.6%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

ammonia
7664-41-7

ammonia

2,2-diamino-4,4,6,6-tetrachlorocyclotriphosphazene
10535-05-4

2,2-diamino-4,4,6,6-tetrachlorocyclotriphosphazene

Conditions
ConditionsYield
In diethyl ether at 0℃; for 1.5h;95%
In diethyl ether; ammonia NH3 (liquid); molar ratio P3N3Cl2:NH3 1:4;
In diethyl ether Schlenk technique;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

4-hydroxy-benzaldehyde
123-08-0

4-hydroxy-benzaldehyde

hexakis(4-formylphenoxy)cyclotriphosphazene
77958-57-7

hexakis(4-formylphenoxy)cyclotriphosphazene

Conditions
ConditionsYield
With caesium carbonate In tetrahydrofuran at 20℃; for 48.5h; Reagent/catalyst; Cooling with ice;94%
Stage #1: 4-hydroxy-benzaldehyde With triethylamine In acetone at 0℃; for 0.5h;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In acetone at 0 - 20℃;
94.19%
With potassium carbonate In tetrahydrofuran for 24h; Reflux;92.8%
In tetrahydrofuran for 48h; Reflux;82%
With sodium hydride In tetrahydrofuran at 65℃; for 48h; Inert atmosphere;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

methyl 4-hydroxylbenzoate
99-76-3

methyl 4-hydroxylbenzoate

hexa(4-carbomethoxyphenoxy)cyclotriphosphazene

hexa(4-carbomethoxyphenoxy)cyclotriphosphazene

Conditions
ConditionsYield
With potassium carbonate In acetone at 80℃;93.6%
With caesium carbonate In tetrahydrofuran for 16h; Reflux; Schlenk technique; Inert atmosphere;79%
hydrogenchloride
7647-01-0

hydrogenchloride

gallium(III) trichloride

gallium(III) trichloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Cl6N3P3*Cl4Ga(1-)*H(1+)

Cl6N3P3*Cl4Ga(1-)*H(1+)

Conditions
ConditionsYield
In chloroform at 20℃; Glovebox; Darkness;92%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2,2,4,4-tetraamino-6,6-dichlorocyclotriphosphazene

2,2,4,4-tetraamino-6,6-dichlorocyclotriphosphazene

Conditions
ConditionsYield
With ammonia at 20℃; for 1.5h;92%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

1-amino-2-propene
107-11-9

1-amino-2-propene

hexakis(allylamino)cyclotriphosphazene
986-11-8

hexakis(allylamino)cyclotriphosphazene

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran for 4h; Inert atmosphere; Reflux;92%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

4-Vinylphenol
2628-17-3

4-Vinylphenol

2,2,4,4,6,6-hexakis-(4-vinyl-phenoxy)-2λ5,4λ5,6λ5-[1,3,5,2,4,6]triazatriphosphinine

2,2,4,4,6,6-hexakis-(4-vinyl-phenoxy)-2λ5,4λ5,6λ5-[1,3,5,2,4,6]triazatriphosphinine

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran at 20 - 60℃; for 23h;91%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

ammonia
7664-41-7

ammonia

A

2,2-diamino-4,4,6,6-tetrachlorocyclotriphosphazene
10535-05-4

2,2-diamino-4,4,6,6-tetrachlorocyclotriphosphazene

B

2,2,4,4-tetraamino-6,6-dichlorocyclotriphosphazene

2,2,4,4-tetraamino-6,6-dichlorocyclotriphosphazene

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1.5h; Solvent;A 1%
B 91%
In diethyl ether at 20℃; for 1.5h; Solvent;A 80%
B 3%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Boc-Tyr-OMe

Boc-Tyr-OMe

C90H120N9O30P3

C90H120N9O30P3

Conditions
ConditionsYield
With caesium carbonate In tetrahydrofuran at 20℃; for 16h; Schlenk technique; Inert atmosphere;91%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2,2'-diaminodiethyl ether
2752-17-2

2,2'-diaminodiethyl ether

1,9,11,11,13,21,23,23-Octachloro-5,17-dioxa-2,8,10,12,14,20,22,24,25,26-decaaza-1λ5,9λ5,11λ5,13λ5,21λ5,23λ5-hexaphospha-tricyclo[19.3.1.19,13]hexacosa-1(25),9,11,13(26),21,23-hexaene
129577-49-7

1,9,11,11,13,21,23,23-Octachloro-5,17-dioxa-2,8,10,12,14,20,22,24,25,26-decaaza-1λ5,9λ5,11λ5,13λ5,21λ5,23λ5-hexaphospha-tricyclo[19.3.1.19,13]hexacosa-1(25),9,11,13(26),21,23-hexaene

Conditions
ConditionsYield
In diethyl ether; water Ambient temperature;90%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

3,6-dioxa-1,8-diaminooctane
929-59-9

3,6-dioxa-1,8-diaminooctane

1,12,14,14,16,27,29,29-Octachloro-5,8,20,23-tetraoxa-2,11,13,15,17,26,28,30,31,32-decaaza-1λ5,12λ5,14λ5,16λ5,27λ5,29λ5-hexaphospha-tricyclo[25.3.1.112,16]dotriaconta-1(31),12,14,16(32),27,29-hexaene
129577-50-0

1,12,14,14,16,27,29,29-Octachloro-5,8,20,23-tetraoxa-2,11,13,15,17,26,28,30,31,32-decaaza-1λ5,12λ5,14λ5,16λ5,27λ5,29λ5-hexaphospha-tricyclo[25.3.1.112,16]dotriaconta-1(31),12,14,16(32),27,29-hexaene

Conditions
ConditionsYield
In diethyl ether; water Ambient temperature;90%
aluminium trichloride
7446-70-0

aluminium trichloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

(PCl2N)3AlCl3

(PCl2N)3AlCl3

Conditions
ConditionsYield
In dichloromethane (under vac.); AlCl3 reacted with (PCl2N)3 in CH2Cl2;90%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

tetraethylene glycol monomethyl ether
23783-42-8

tetraethylene glycol monomethyl ether

2,2,4,4,6,6-hexakis-(2-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)ethoxy)cyclotriphosphazene
1289636-24-3

2,2,4,4,6,6-hexakis-(2-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)ethoxy)cyclotriphosphazene

Conditions
ConditionsYield
Stage #1: tetraethylene glycol monomethyl ether With sodium hydride In 1,4-dioxane at 50℃; for 24h; Inert atmosphere;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In 1,4-dioxane at 60℃; for 48h; Inert atmosphere;
90%
hydrogenchloride
7647-01-0

hydrogenchloride

aluminum (III) chloride
7446-70-0, 7784-13-6

aluminum (III) chloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Cl6N3P3*AlCl4(1-)*H(1+)

Cl6N3P3*AlCl4(1-)*H(1+)

Conditions
ConditionsYield
In chloroform at 21.84℃; Schlenk technique; Glovebox;90%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2-[tricarbonyl(η(6)-phenoxy)chromium]ethanol
134177-52-9

2-[tricarbonyl(η(6)-phenoxy)chromium]ethanol

sodium hydride
7646-69-7

sodium hydride

N3P3{(η6-OCH2CH2OC6H5)Cr(CO)3}6
134208-38-1

N3P3{(η6-OCH2CH2OC6H5)Cr(CO)3}6

Conditions
ConditionsYield
In tetrahydrofuran (N2), added at 0. degree.C, warmed to 25°C and stirred for 5 h, added dropwise N3P3Cl6, stirred at 40-45°C for 12 h; removed solvent in vac., column chromy.; elem. anal., IR, mass. spectra,NMR;89%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

(Z)-oct-5-en-1-ol
64275-73-6

(Z)-oct-5-en-1-ol

2,2,4,4,6,6-hexakis-(cis-5-octenyl-1-oxy)cyclotriphosphazene
1289636-29-8

2,2,4,4,6,6-hexakis-(cis-5-octenyl-1-oxy)cyclotriphosphazene

Conditions
ConditionsYield
Stage #1: (Z)-oct-5-en-1-ol With sodium hydride In 1,4-dioxane at 50℃; for 24h; Inert atmosphere;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In 1,4-dioxane at 60℃; for 48h; Inert atmosphere;
89%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2-Allylphenol
1745-81-9

2-Allylphenol

C54H54N3O6P3

C54H54N3O6P3

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran at 20 - 60℃; for 13.5h;89%
5,5-difluoro-10-(4-hydroxyphenyl)-5H-dipyrrolo[1,2-c :2’,1’-f][1,3,2]diazaborinin-4-ium-5-uide

5,5-difluoro-10-(4-hydroxyphenyl)-5H-dipyrrolo[1,2-c :2’,1’-f][1,3,2]diazaborinin-4-ium-5-uide

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hexakis[4,4-difluoroboryl-8-(p-phenoxy)-4-bora-3a,4a-diaza-s-indacene]cyclotriphosphazene

hexakis[4,4-difluoroboryl-8-(p-phenoxy)-4-bora-3a,4a-diaza-s-indacene]cyclotriphosphazene

Conditions
ConditionsYield
With Cs2CO3 In tetrahydrofuran hydroxyphenyl and Cs2CO3 was added to hexachlorotriphosphazene in THF at0°C, stirred for 6 h at 50°C; concd. in vac., column chromy. (silica, CH2Cl2), evapd. in vac.;88%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2,2'-dihydroxybiphenyl
1806-29-7

2,2'-dihydroxybiphenyl

4',4',6',6'-tetrachloro-4'λ5,6λ5,6'λ5-spiro[dibenzo[d,f][1–3]-dioxaphosphepine-6,2'-[1–6]triazatriphosphinine]
128175-79-1

4',4',6',6'-tetrachloro-4'λ5,6λ5,6'λ5-spiro[dibenzo[d,f][1–3]-dioxaphosphepine-6,2'-[1–6]triazatriphosphinine]

Conditions
ConditionsYield
In acetone at 20℃; for 0.25h;87%
With caesium carbonate In tetrahydrofuran at 20℃; for 10h;
With potassium carbonate
C16H20NPO4
918636-17-6

C16H20NPO4

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

C96H114N9O24P9

C96H114N9O24P9

Conditions
ConditionsYield
With caesium carbonate In acetonitrile at 20℃; for 24h;87%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

aluminium bromide
7727-15-3

aluminium bromide

(PCl2N)3AlBr3

(PCl2N)3AlBr3

Conditions
ConditionsYield
In dichloromethane (under vac.); AlBr3 reacted with (PCl2N)3 in CH2Cl2;87%

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