118436-92-3Relevant academic research and scientific papers
Stereoselectivity in the Lewis acid mediated reduction of ketofuranoses
Van Rijssel, Erwin R.,Van Delft, Pieter,Van Marle, Daan V.,Bijvoets, Stefan M.,Lodder, Gerrit,Overkleeft, Herman S.,Van Der Marel, Gijsbert A.,Filippov, Dmitri V.,Codée, Jeroen D.C.
, p. 4553 - 4565 (2015)
The Lewis acid mediated reduction of ribose-, arabinose-, xylose-, and lyxose-derived methyl and phenyl ketofuranoses with triethylsilane as nucleophile was found to proceed with good to excellent stereoselectivity to provide the 1,2-cis addition products
C-Glycosides. 7. Stereospecific C-Glycosylation of Aromatic and Heterocyclic Rings
Czernecki, S.,Ville, G.
, p. 610 - 612 (2007/10/02)
Stereospecific C-glycosylation of aromatic and heterocyclic rings can be realized by reacting the corresponding organolithium derivatives with benzylated lactones and reducing the so-obtained lactols with triethylsilane in the presence of boron trifluorid
