Stereoselectivity in the Lewis acid mediated reduction of ketofuranoses

DOI: 10.1021/acs.joc.5b00419

Source and publish data:

Journal of Organic Chemistry p. 4553 - 4565 (2015)

Update date:2022-07-30

Topics:

Authors:

Van Rijssel, Erwin R.

Van Delft, Pieter

Van Marle, Daan V.

Bijvoets, Stefan M.

Lodder, Gerrit

Overkleeft, Herman S.

Van Der Marel, Gijsbert A.

Filippov, Dmitri V.

Codée, Jeroen D.C.

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Article abstract of DOI:10.1021/acs.joc.5b00419

The Lewis acid mediated reduction of ribose-, arabinose-, xylose-, and lyxose-derived methyl and phenyl ketofuranoses with triethylsilane as nucleophile was found to proceed with good to excellent stereoselectivity to provide the 1,2-cis addition products

Full text of DOI:10.1021/acs.joc.5b00419

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