118451-59-5

Basic information

• Product Name: ethyl 4,5-dimethylcyclohexa-1,4-dienecarboxylate
• Synonyms: ethyl 4,5-dimethylcyclohexa-1,4-dienecarboxylate
• CAS NO: 118451-59-5
• Molecular Weight: 180.247
• Mol File: 118451-59-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ethyl 4,5-dimethylcyclohexa-1,4-dienecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4,5-dimethylcyclohexa-1,4-dienecarboxylate(118451-59-5)
• EPA Substance Registry System: ethyl 4,5-dimethylcyclohexa-1,4-dienecarboxylate(118451-59-5)

Safety Data

• Hazardous Substances Data: 118451-59-5(Hazardous Substances Data)

Upstream product

• 42216-95-5 2-bromo-1,1,1-triethoxypropane 
• 42216-99-9 Triethyl-2,3-dibrom-orthopropanoat 
• 42216-96-6 triethyl orthoacrylate 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 623-47-2 propynoic acid ethyl ester 

Downstream Products

• 67086-96-8 (4,5-dimethylcyclohexa-1,4-dienyl)methanol 

Relevant articles and documents

Pentacenequinone-stabilized silver nanoparticles: A reusable catalyst for the diels-alder [4 + 2] cycloaddition reactions

Silver nanoparticles (AgNPs) stabilized by aggregates of derivative 4 have been used as catalyst for the construction of synthetically and biologically important [4 + 2] cycloadducts at room temperature.

Ethynyl Ortho Esters as Precursors of Propargyl Cations. The Low-Temperature, Ionic Diels-Alder Addition of Ethyl Propiolate to 1,3-Dienes via Ethynyl Ortho Esters

3,3,3-Triethoxypropyne (triethyl orthopropiolate) was added to a series of 1,3-dienes at low temperature in the presence of trimethylsilyl triflate to yield the 4? + 2? products of the formal addition of ethyl propiolate to the 1,3-dienes.