118527-80-3Relevant academic research and scientific papers
ON THE REGIOSELECTIVITY IN THE SILYL GROUP DIRECTED BAEYER-VILLIGER REACTION
Aida, Toshiaki,Asaoka, Morio,Sonoda, Syuzo,Takei, Hisashi
, p. 427 - 430 (2007/10/02)
In the Baeyer-Villiger reaction of 3,5-bis-silylated cyclohexanones, preferential migration of the less substituted α-carbon was observed.
3-Substituted-γ-butyrolactones from 5-Trimethylsilyl-2-cyclohexenone. Synthesis of (-)-Enterolactone
Asaoka, Morio,Fujii, Naoaki,Shima, Kunihisa,Takei, Hisashi
, p. 805 - 808 (2007/10/02)
1,4-Adducts of 5-trimethylsilyl-2-cyclohexenone (1) with Grignard reagents were converted to various hexanoate derivatives and γ-butyrolactones.Starting from optically pure 1, (-)-enterolactone (Factor X) was synthesized.
