118535-81-2

Upstream product

• 118535-84-5 [(S)-2-Benzyloxy-oct-(Z)-ylidene]-[(S)-2-(1-methoxy-1-methyl-ethyl)-pyrrolidin-1-yl]-amine 
• 118535-86-7 [(S)-2-Benzyloxy-oct-(Z)-ylidene]-[(S)-2-(1-ethyl-1-methoxy-propyl)-pyrrolidin-1-yl]-amine 
• 924288-69-7 7,10-bis-benzyloxy-hexadecane-8,9-diol 
• 924288-66-4 1-(5-heptanoyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-heptan-1-one 
• 118535-67-4 [(S)-2-(1-Ethyl-1-methoxy-propyl)-pyrrolidin-1-yl]-oct-(Z)-ylidene-amine 
• 118535-66-3 [(S)-2-(1-Methoxy-1-methyl-ethyl)-pyrrolidin-1-yl]-oct-(Z)-ylidene-amine 
• 124-13-0 Octanal 
• 924288-68-6 4,5-bis-(1-benzyloxy-heptyl)-2,2-dimethyl-[1,3]dioxolane 
• 924288-67-5 1-[5-(1-hydroxy-heptyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-heptan-1-ol 

Downstream Products

• 852509-25-2 (4R,5R)-4,5-dibenzyloxyhept-6-enoic acid (1'S,1''S)-1'-(1''-benzyloxyheptyl)-3'-butenyl ester 
• 852509-26-3 (5R,6R,7E,10S)-10-[(1'S)-1'-benzyloxyheptyl]-5,6-dibenzyloxy-3,4,5,6,9,10-hexahydro-2H-oxecin-2-one 
• 675127-22-7 1-[1-benzyloxy-(1S)-heptyl]-(1S)-3-butenyl alcohol 

Relevant academic research and scientific papers

Stereoselective synthesis of (-)-microcarpalide

A stereoselective approach for the synthesis of the bio-active decanolactone (-)-microcarpalide was achieved from chiral pool tartaric acid. The synthesis of pivotal intermediates en route to the decanolactone was achieved from α-benzyloxy aldehydes deriv

ENANTIOSELECTIVE SYNTHESIS OF PROTECTED α-HYDROXY ALDEHYDES AND KETONES VIA HYDROXYLATION OF METALATED CHIRAL HYDRAZONES

α-Benzyloxy aldehydes and α-acetoxy ketones 4 of high enantiomeric purity are prepared in good overall yields via oxaziridine mediated hydroxylation of chiral hydrazone azaenolates.As auxiliaries novel proline derived hydrazine reagents 5 are used.