852509-26-3

Upstream product

• 924288-66-4 1-(5-heptanoyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-heptan-1-one 
• 924288-67-5 1-[5-(1-hydroxy-heptyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-heptan-1-ol 
• 852509-24-1 (4R,5R)-4,5-dibenzyloxyhept-6-enoic acid tert-butyl ester 
• 675127-22-7 1-[1-benzyloxy-(1S)-heptyl]-(1S)-3-butenyl alcohol 
• 553664-97-4 (4R,5R)-4,5-bis(benzyloxy)hept-6-enoic acid 
• 553665-24-0 (4R,5R)-4,5-bis(benzyloxy)hept-6-en-1-ol 
• 118535-81-2 (S)-2-Benzyloxy-octanal 
• 924288-72-2 (3R,4R)-4-(benzyloxy)-7-((tert-butyldiphenylsilyl)oxy)hept-1-en-3-ol 
• 874910-05-1 (4R,5R)-4,5-bis(pent-4-enoyl)-2,2-dimethyl-1,3-dioxolane 
• 852509-25-2 (4R,5R)-4,5-dibenzyloxyhept-6-enoic acid (1'S,1''S)-1'-(1''-benzyloxyheptyl)-3'-butenyl ester 
• 924288-73-3 4,5-bis-[1-benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-butyl]-2,2-dimethyl-[1,3]dioxolane 
• 924288-71-1 4,7-bis-benzyloxy-1,10-bis-(tert-butyl-diphenyl-silanyloxy)-decane-5,6-diol 
• 924288-70-0 4-benzyloxy-4-[5-(1-benzyloxy-4-hydroxy-butyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-butan-1-ol 
• 924288-74-4 (4,5-bis-benzyloxy-hept-6-enyloxy)-tert-butyl-diphenyl-silane 

Relevant academic research and scientific papers

Stereoselective synthesis of (-)-microcarpalide

A stereoselective approach for the synthesis of the bio-active decanolactone (-)-microcarpalide was achieved from chiral pool tartaric acid. The synthesis of pivotal intermediates en route to the decanolactone was achieved from α-benzyloxy aldehydes deriv

Enantioselective total synthesis of (-)-microcarpalide

The enantioselective total synthesis of the actin-targeting metabolite (-)-microcarpalide is described. Key steps include ring-closing metathesis (RCM) for the final construction of the 10-membered lactone framework and stereoselective homologation of bor