1185446-84-7Relevant academic research and scientific papers
PdII catalyzed ligand controlled synthesis of bis(3-furanyl)methanones and methyl 3-furancarboxylates
Kusakabe, Taichi,Mochida, Tomoyuki,Ariyama, Tomohiro,Lee, Dong,Ohkubo, Shin,Takahashi, Keisuke,Kato, Keisuke
, p. 6860 - 6865 (2019/07/22)
The PdII catalyzed carbonylation of allenyl ketones has been investigated. Carbonylative dimerization predominantly proceeded to afford bis(3-furanyl)methanones 2 as the major products. The use of DMSO strikingly changed the course of the react
Palladium(II) catalyzed carbonylative dimerization of allenyl ketones: efficient synthesis of difuranylketones
Kato, Keisuke,Mochida, Tomoyuki,Takayama, Hiroyuki,Kimura, Masayuki,Moriyama, Hiroshi,Takeshita, Akihito,Kanno, Yuichro,Inouye, Yoshio,Akita, Hiroyuki
supporting information; experimental part, p. 4744 - 4746 (2011/03/18)
Palladium(II) catalyzed carbonylation of 1,2-allenyl ketones 1 in the presence of p-benzoquinone (1 equiv) under a CO atmosphere (balloon) afforded difuranylketones 4 in moderate to good yields. Mechanistically, the electron-withdrawing nature of the acyl
