1185447-01-1Relevant academic research and scientific papers
Palladium(II) catalyzed carbonylative dimerization of allenyl ketones: efficient synthesis of difuranylketones
Kato, Keisuke,Mochida, Tomoyuki,Takayama, Hiroyuki,Kimura, Masayuki,Moriyama, Hiroshi,Takeshita, Akihito,Kanno, Yuichro,Inouye, Yoshio,Akita, Hiroyuki
, p. 4744 - 4746 (2009)
Palladium(II) catalyzed carbonylation of 1,2-allenyl ketones 1 in the presence of p-benzoquinone (1 equiv) under a CO atmosphere (balloon) afforded difuranylketones 4 in moderate to good yields. Mechanistically, the electron-withdrawing nature of the acyl
