118574-91-7

Upstream product

• 118574-89-3 (2R,3S)-3-Benzyloxymethyl-2-methyl-oxirane-2-carbaldehyde 
• 118574-88-2 ((2S,3S)-3-Benzyloxymethyl-2-methyl-oxiranyl)-methanol 
• 70238-41-4 (E)-4-(benzyloxy)-2-methylbut-2-en-1-ol 
• 118574-90-6 (Z)-3-((2S,3S)-3-Benzyloxymethyl-2-methyl-oxiranyl)-acrylic acid ethyl ester 

Downstream Products

• 115827-32-2 2-Benzyloxy-1-(2-methyl-2,5-dihydro-furan-2-yl)-ethanol 
• 132409-59-7 (Z)-(4R,5R)-6-(Benzyloxy)-4,5-epoxy-4-methyl-1-<(methylthio)methoxy>-2-hexene 
• 115827-42-4 C₂₉H₃₄O₃ 
• 115827-42-4 C₂₉H₃₄O₃ 
• 115857-49-3 (Z)-(2S,5R)-6-Benzyloxy-2,4-dimethyl-hex-3-ene-1,5-diol 
• 118508-93-3 (E)-(2R,5R)-6-Benzyloxy-2,4-dimethyl-hex-3-ene-1,5-diol 
• 132409-50-8 (E)-(2R,5S)-6-(Benzyloxy)-2,4-dimethyl-5-hydroxy-1-<(methylthio)methoxy>-3-hexene 
• 132409-56-4 (Z)-(2S,5R)-1-Benzyloxy-3,5-dimethyl-6-methylsulfanylmethoxy-hex-3-en-2-ol 
• 132409-52-0 (E)-(2S,5S)-6-(Benzyloxy)-2,4-dimethyl-5-hydroxy-1-<(methylthio)methoxy>-3-hexene 
• 132409-53-1 (E)-(5S)-6-(benzyloxy)-4-methyl-1,3-hexadien-5-ol 
• 115827-34-4 (E)-(S)-6-Benzyloxy-4,4-dimethyl-hex-2-ene-1,5-diol 
• 115827-41-3 (E)-(2S,5S)-6-(benzyloxy)-2,4-dimethyl-3-hexene-1,5-diol 
• 115827-35-5 (E)-(2R,5S)-6-(benzyloxy)-2,4-dimethyl-3-hexene-1,5-diol 

Relevant academic research and scientific papers

HIGHLY ANTISELECTIVE SN2' ADDITIONS OF LiMe2Cu TO CHIRAL ACYCLIC VINYLOXIRANES

Additions of LiMe2Cu to the trans and cis-Z vinyloxiranes 8 and 10 proceed with virtually 100percent anti diastereoface selectivity to afford the syn-Z diol 12 and the anti-E diol 13 as the major products.