118574-89-3

Upstream product

• 118574-88-2 ((2S,3S)-3-Benzyloxymethyl-2-methyl-oxiranyl)-methanol 
• 70238-41-4 (E)-4-(benzyloxy)-2-methylbut-2-en-1-ol 
• 115936-20-4 [(2S,3R)-3-[(benzyloxy)methyl]-2-methyloxiran-2-yl]methanol 

Downstream Products

• 132409-22-4 (3S,4R)-5-(Benzyloxy)-1,1-dibromo-3,4-epoxy-3-methyl-1-pentene 
• 132409-33-7 (5S,6R)-7-(Benzyloxy)-5,6-epoxy-5-methyl-3-hepten-2-one 
• 118574-90-6 (Z)-3-((2S,3S)-3-Benzyloxymethyl-2-methyl-oxiranyl)-acrylic acid ethyl ester 
• 115827-42-4 C₂₉H₃₄O₃ 
• 115827-42-4 C₂₉H₃₄O₃ 
• 118508-93-3 (E)-(2R,5R)-6-Benzyloxy-2,4-dimethyl-hex-3-ene-1,5-diol 
• 115857-49-3 (Z)-(2S,5R)-6-Benzyloxy-2,4-dimethyl-hex-3-ene-1,5-diol 
• 118574-91-7 (Z)-3-((2S,3S)-3-Benzyloxymethyl-2-methyl-oxiranyl)-prop-2-en-1-ol 
• 132409-30-4 [(E)-3-((2S,3R)-3-Benzyloxymethyl-2-methyl-oxiranyl)-1-methyl-allyloxy]-tert-butyl-dimethyl-silane 
• 132409-30-4 [(Z)-3-((2S,3R)-3-Benzyloxymethyl-2-methyl-oxiranyl)-1-methyl-allyloxy]-tert-butyl-dimethyl-silane 
• 132409-31-5 (2S,3R)-3-Benzyloxymethyl-2-methyl-2-((E)-3-methylsulfanylmethoxy-but-1-enyl)-oxirane 
• 132409-31-5 (2S,3R)-3-Benzyloxymethyl-2-methyl-2-((Z)-3-methylsulfanylmethoxy-but-1-enyl)-oxirane 
• 132409-36-0 (E)-(S)-1-Benzyloxy-3,5-dimethyl-6-methylsulfanylmethoxy-hept-3-en-2-ol 
• 132409-35-9 (E)-(2S,5R,6S)-1-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hept-3-en-2-ol 

Relevant academic research and scientific papers

HIGHLY ANTISELECTIVE SN2' ADDITIONS OF LiMe2Cu TO CHIRAL ACYCLIC VINYLOXIRANES

Additions of LiMe2Cu to the trans and cis-Z vinyloxiranes 8 and 10 proceed with virtually 100percent anti diastereoface selectivity to afford the syn-Z diol 12 and the anti-E diol 13 as the major products.

Diastereodifferentiation in SN2' Additions of Methylcuprates to Nonracemic Acyclic Vinyloxiranes

SN2' additions of Me2CuLi, MeCu(CN)Li, and Me2Cu(CN)Li2 to the 2S and 2R alkoxy cis-(Z)- and -(E)-vinyloxiranes 8, 9, 13, and 14 were examined as possible routes to acyclic subunits of polypropionate natural products.Highest anti:syn ratios wer