1185984-59-1

Basic information

• Product Name: benzyl (R)-2-(nitromethyl)-4-oxo-4-phenylbutanoate
• Synonyms: benzyl (R)-2-(nitromethyl)-4-oxo-4-phenylbutanoate
• CAS NO: 1185984-59-1
• Molecular Weight: 327.337
• Mol File: 1185984-59-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl (R)-2-(nitromethyl)-4-oxo-4-phenylbutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl (R)-2-(nitromethyl)-4-oxo-4-phenylbutanoate(1185984-59-1)
• EPA Substance Registry System: benzyl (R)-2-(nitromethyl)-4-oxo-4-phenylbutanoate(1185984-59-1)

Safety Data

• Hazardous Substances Data: 1185984-59-1(Hazardous Substances Data)

Upstream product

• 622-00-4 dibenzyl (+)-tartrate 
• 52709-42-9 benzylglyoxylate 
• 75-52-5 nitromethane 
• 86633-21-8 (E)-benzyl 4-phenyl-4-oxo-2-butenoate 

Downstream Products

• 1185985-41-4 benzyl (R)-3-nitro-2-[(2-phenyl-1,3-dithiolan-2-yl)methyl]propanoate 

Relevant articles and documents

Highly enantioselective organocatalytic Michael addition of nitroalkanes to 4-oxo-enoates

A useful Michael addition reaction using nitroalkanes as the nucleophile and 4-oxo-enoates as the Michael acceptor has been disclosed, and the reaction allows expedient access to functionalized chiral γ-keto esters in high yields and excellent enantioselectivities (up to 98% ee), with a low catalyst loading.