1186139-51-4

Basic information

• Product Name: C₂₀H₃₂N₃OP
• Synonyms: C₂₀H₃₂N₃OP
• CAS NO: 1186139-51-4
• Molecular Weight: 361.467
• Mol File: 1186139-51-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₀H₃₂N₃OP(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₃₂N₃OP(1186139-51-4)
• EPA Substance Registry System: C₂₀H₃₂N₃OP(1186139-51-4)

Safety Data

• Hazardous Substances Data: 1186139-51-4(Hazardous Substances Data)

Upstream product

• 137944-38-8 (1R,2R)-N,N'-bis(1'-methylethyl)-1,2-cyclohexanediamine 

Downstream Products

• 1434076-69-3 C₂₃H₃₆N₃O₃P 
• 1255703-24-2 C₂₄H₄₃N₃O₄P₂ 
• 1310539-59-3 C₂₁H₃₃N₄OP 
• 1281868-04-9 C₂₅H₄₂N₃OPS₂ 
• 1281868-03-8 C₂₄H₄₀N₃OPS₂ 
• 1186139-63-8 C₃₇H₄₉N₄O₃P 

Relevant articles and documents

Synthesis of Diastereoenriched α-Aminomethyl Enaminones via a Br?nsted Acid-Catalyzed Asymmetric aza-Baylis-Hillman Reaction of Chiral N-Phosphonyl Imines

An effective chiral GAP methodology for preparing α-aminomethyl enaminones through a (R)-CSA-catalyzed asymmetric aza-Baylis-Hillman reaction is reported. Excellent yields and high diastereoselectivity could be obtained under mild conditions and convenient GAP techniques. The confirmations of the absolute configuration of N-phosphonyl imine and chiral enaminone by X-ray diffraction provides an explicit explanation of the chirality mechanism for GAP chemistry.