118684-46-1Relevant academic research and scientific papers
Vicarious Nucleophilic Substitution of Hydrogen in Nitro-1,6-methanoannulenes
Ostrowski, S.,Moritz, R. J.,Mudryk, B.
, p. 447 - 460 (2007/10/02)
The 2- and 3-nitro-1,6-methanoannulenes and their 11,11-difluoro derivatives react with carbanions bearing leaving groups at the carbanionic center according to the Vicarious Nucleophilic Substitution of Hydrogen (VNS) scheme.The analogy between corre
Nucleophilic C-C Linkages of 2-Nitro- and 3-Nitro-1,6-methanoannulenes
Neidlein, Richard,Lautenschlaeger, Gabriele
, p. 493 - 498 (2007/10/02)
By "vicarious nucleophilic substitutions" of 2- and 3-nitro-1,6-methanoannulenes (2, 3) the new compounds 4 - 13 are obtained.Reactions of 2, 3 with sodium methoxide lead to the Ethers 16 and 17, oxidative coupling reactions in the presence of MnO2 to 18, and Meisenheimer complexes, followed by oxidation to the nitromethane derivatives 14 and 15. - Keywords: 1,6-Methanoannulenes, 2- and 3-nitro/ Vicarious nucleophilic substitution
