118712-13-3

Basic information

• Product Name: (E,1R,5S)-3-(4-methoxybenzylidene)-6,6-dimethylbicyclo[3.1.1]heptan-2-one
• Synonyms: (E,1R,5S)-3-(4-methoxybenzylidene)-6,6-dimethylbicyclo[3.1.1]heptan-2-one
• CAS NO: 118712-13-3
• Molecular Weight: 256.345
• Mol File: 118712-13-3.mol

Chemical Properties

• CAS DataBase Reference: (E,1R,5S)-3-(4-methoxybenzylidene)-6,6-dimethylbicyclo[3.1.1]heptan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E,1R,5S)-3-(4-methoxybenzylidene)-6,6-dimethylbicyclo[3.1.1]heptan-2-one(118712-13-3)
• EPA Substance Registry System: (E,1R,5S)-3-(4-methoxybenzylidene)-6,6-dimethylbicyclo[3.1.1]heptan-2-one(118712-13-3)

Safety Data

• Hazardous Substances Data: 118712-13-3(Hazardous Substances Data)

Upstream product

• 38651-65-9 (1R,5S)-(+)-nopinone 
• 123-11-5 4-methoxy-benzaldehyde 
• 18172-67-3 beta-pinene 

Downstream Products

• 188851-34-5 (1R,2R,3S,5S)-3-(4-Methoxy-benzyl)-6,6-dimethyl-bicyclo[3.1.1]heptan-2-ol 
• 881426-03-5 (1R,2R,3S,5S,1'R)-3-(1'-(4-methoxyphenyl)ethyl)-6,6-dimethylbicyclo[3.1.1]heptan-2-ol 
• 881426-02-4 (1R,3S,5S,1'R)-3-(1'-(4-methoxyphenyl)ethyl)-6,6-dimethylbicyclo[3.1.1]heptan-2-one 
• 188851-30-1 (1R,3S,5S)-3-(4-Methoxy-benzyl)-6,6-dimethyl-bicyclo[3.1.1]heptan-2-one 

Relevant articles and documents

Synthesis and structural determination of new chiral auxiliaries derived from (-)-β-pinene

New chiral auxiliaries, alcohols syn-11a,e and anti-12a,e, were readily synthesized in a stereoselective manner from (-)-β-pinene. Their stereochemical determinations have been made on the basis of nOe experiments.