118722-39-7Relevant academic research and scientific papers
Thermal Stability and Fluxional Behaviour of Bicyclic Sulphur-Nitrogen Structures of Formula EN5S3 (E = CR, PR2, or SO2-)
Boere, Rene T.,Oakley, Richard T.,Shevalier, Maurice
, p. 110 - 112 (1987)
Two thermally induced N-S bond cleavage processes are available to EN5S3 heterocycles: (i) an irreversible loss of NSN to form EN3S2 (for E = PR2 and SO2-) and (ii) a pseudo-degenerate 1,3-nitrogen shift which exchanges all nitrogen atoms (for E = CPh).
Degenerate and Pseudodegenerate 1,3-Nitrogen Shifts in Sulfur-Nitrogen Chemistry: (15)N NMR Analysis of Skeletal Scrambling in PhCN5S3
Bestari, Ketut T.,Boere, Rene T.,Oakley, Richard T.
, p. 1579 - 1584 (1989)
Skeletal scrambling in the 1,3-NSN-bridged 5-phenyl-1,3,2,4,6-dithiatriazine (PhCN5S3) has been studied by NMR analysis of the exchange of (15)N-labeled nitrogen between different sites.A mechanism involving two simultaneous 1,3-nitrogen shift pathways, v
1,3-Nitrogen Shift Reaction in Sulfur-Nitrogen Chemistry. Preparation and Interconversion of exo- and endo-Trithiatatrazocines
Boere, Rene T.,Cordes, A. Wallac,Oakley, Richard T.
, p. 7781 - 7785 (2007/10/02)
The reaction of the 1,3-NSN-bridged 5-phenyl-1,3,2,4,6-dithiatriazine PhCN5S3 with tertiary phosphines and triphenylarsine has been studied by 31P and 15N NMR spectroscopy.The mechanism of formation of the final product, th
