Journal of the Chemical Society. Chemical communications p. 110 - 112 (1987)
Update date:2022-08-04
Topics:
Boere, Rene T.
Oakley, Richard T.
Shevalier, Maurice
Two thermally induced N-S bond cleavage processes are available to EN5S3 heterocycles: (i) an irreversible loss of NSN to form EN3S2 (for E = PR2 and SO2-) and (ii) a pseudo-degenerate 1,3-nitrogen shift which exchanges all nitrogen atoms (for E = CPh).
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