1187364-06-2Relevant academic research and scientific papers
Dehydrogenative heck reaction of furans and thiophenes with styrenes under mild conditions and influence of the oxidizing agent on the reaction rate
Vasseur, Alexandre,Muzart, Jacques,Le Bras, Jean
supporting information; experimental part, p. 12556 - 12560 (2011/12/04)
CiH vs. CiBr in Heck: The direct dehydrogenative coupling of furans and thiophenes with styrenes occurs under mild conditions (see scheme). This method allows the coupling of brominated substrates through CiH bond activation. In addition, DMSO and benzoquinone had a positive effect on the reaction rate.
Palladium-catalyzed dehydrogenative coupling of furans with styrenes
Aouf, Chahinez,Thiery, Emilie,Le Bras, Jean,Muzart, Jacques
supporting information; experimental part, p. 4096 - 4099 (2009/12/06)
Under palladium(II)-catalyzed and oxidative conditions, the coupling of furans with styrenes leads to the formation of Heck-type products In medium to good yields. The reaction Is highly regio- and stereoselective, giving frans-olefins predominantly.
