118739-75-6Relevant academic research and scientific papers
OXIDATIONS BY METHYL TRIFLUOROMETHYL DIOXIRANE. EPOXIDATION OF ENOL ETHERS
Troisi, Luigino,Cassidei, Luigi,Lopez, Luigi,Mello, Rossella,Curci, Ruggero
, p. 257 - 260 (2007/10/02)
Isolated methyl trifluoromethyl dioxirane 4b has been employed to achieve the rapid, low temperature epoxidation of enol ethers, such as alkoxy(aryl)methylidene adamantanes 1a-e and methoxy(2-naphtyl)methylidene 2-bornane 1f, affording the corresponding spirooxiranes in excellent (92-97percent) yields.
OXIDATION OF ENOL ETHERS BY METAL(VI)OXIDE DIPEROXIDES
Curci, Ruggero,Lopez, Luigi,Troisi, Luigino,Rashid, S. M. Khaledur,Schaap, A. Paul
, p. 3145 - 3148 (2007/10/02)
Alkoxy(aryl) adamantylidenes react with chromium(VI) or molybdenum(VI) oxide diperoxides in CHCl3 under argon yielding the corresponding 1,2-dioxetanes and/or carbonyl products derived from the fragmentation of the dioxetanes.The reaction most likely proceeds via preliminary epoxidation of the unsaturated substrates.
