113849-79-9

Basic information

• Product Name: 1-(2-Adamantylidene)-1-methoxy-1-phenylmethane
• Synonyms: 1-(2-Adamantylidene)-1-methoxy-1-phenylmethane
• CAS NO: 113849-79-9
• Molecular Weight: 254.372
• Mol File: 113849-79-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(2-Adamantylidene)-1-methoxy-1-phenylmethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-Adamantylidene)-1-methoxy-1-phenylmethane(113849-79-9)
• EPA Substance Registry System: 1-(2-Adamantylidene)-1-methoxy-1-phenylmethane(113849-79-9)

Safety Data

• Hazardous Substances Data: 113849-79-9(Hazardous Substances Data)

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 186821-36-3 4'-Ethoxy-4'-(3-hydroxyphenyl)spiro[adamantane-2,3'-[1,2]dioxetane] 
• 298704-07-1 1-(2-Adamantylidene)-1-ethoxy-1-(3-hydroxyphenyl)methane 
• 100-52-7 benzaldehyde 
• 700-58-3 2-Adamantanone 
• 132205-80-2 dimethyl phosphonate 
• 68157-27-7 adamantan-2-yl(phenyl)methanone 
• 74-88-4 methyl iodide 

Downstream Products

• 93-58-3 benzoic acid methyl ester 
• 700-58-3 2-Adamantanone 
• 118739-75-6 C₁₈H₂₂O₂ 
• 113849-81-3 4-methoxy-(1-phenyl)spiro<1,2-dioxetane-3,2'-adamantane> 
• 67-56-1 methanol 
• 68157-27-7 adamantan-2-yl(phenyl)methanone 
• 82027-25-6 (2-Hydroxy-adamantan-2-yl)-phenyl-methanone 

Relevant articles and documents

Use of the Wadsworth-Emmons reaction for preparing hindered vinyl ethers and related 1,2-dioxetanes

Arylaldehyde acctals can be reacted with trimethyl phosphite to produce the corresponding dimethyl α-methoxy-benzylphosphonates, themselves used in a Wadsworth-Emmons reaction with adamantanone to produce hindered methyl vinyl ethers. These vinyl ethers are useful in the preparation of chemiluminescent 1,2-dioxetanes. The scope of the reaction has been explored.