1187643-58-8Relevant academic research and scientific papers
Iridium phosphinidene complexes: A comparison with iridium imido complexes in their reaction with isocyanides
Aktas, Halil,Mulder, Jos,De Kanter, Frans J. J.,Slootweg, J. Chris,Schakel, Marius,Ehlers, Andreas W.,Lutz, Martin,Spek, Anthony L.,Lammertsma, Koop
, p. 13531 - 13537 (2009)
18-Electron nucleophilic, Schrock-type phosphinidene complexes 3 [Cp*(Xy-N≡C)Ir=PAr] (Ar = Mes*, Dmp, Mes) are capable of unprecedented [1 + 2]-cycloadditions with 1 equiv of isocyanide RNC (R = Xy, Ph) to give novel iridaphosphirane complexes [Cp*(Xy-N≡C
