118792-79-3Relevant academic research and scientific papers
Practical and efficient synthesis of C2 symmetrical diamines with Zn / Me3SiCl
Alexakis, Alexandre,Aujard, Isabelle,Mangeney, Pierre
, p. 873 - 874 (1998)
C2 symmetrical diamines are efficiently obtained by reductive coupling of imines with the couple Zn/Me3SiCl. This high yielding method is very practical and cheap for large scale preparation.
Titanium Induced Coupling of Imines to Symmetrical Vicinal (R*,R*)-Diamines
Mangeney, P.,Tejero, T.,Alexakis, A.,Grosjean, F.,Normant, J.
, p. 255 - 257 (2007/10/02)
Symmetrical vicinal (R*,R*) -d,l-diamines were prepared from the corresponding imines and low valent titanium species generated by the action of titanium tetrachloride on amalgamated magnesium.
