118824-31-0Relevant articles and documents
Short Total Synthesis of Ajoene
Silva, Filipa,Khokhar, Shaista S.,Williams, Danielle M.,Saunders, Robert,Evans, Gareth J. S.,Graz, Michael,Wirth, Thomas
supporting information, p. 12290 - 12293 (2018/09/18)
We describe a short total synthesis of ajoene, a major biologically active constituent of garlic. The instability of allicin as the only other known alternative starting material has led to the development of a reliable procedure for the synthesis of ajoene from simple building blocks that is also suitable for upscale operations.
SYNTHESIS OF SPIROETHERS USING RADICAL CYCLISATIONS
Middleton, Donald S.,Simpkins, Nigel S.,Begley, Michael J.,Terrett, Nicholas K.
, p. 545 - 564 (2007/10/02)
A variety of spiroether products, including one bis-spiro compound, are avaible via a simple radical cyclisation route.