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Upstream product

• 135-19-3 β-naphthol 
• 4221-98-1 (R)-5-isopropyl-2-methylcyclohexa-1,3-diene 
• 1252606-18-0 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octane-2,5-diene-2-carboxylic acid 
• 99-83-2 p-mentha-1,5-diene 
• 91805-17-3 naphthalen-2-yl prop-2-ynoate 
• 1184-58-3 dimethylaluminum chloride 

Downstream Products

• 1063949-39-2 (1R,4R,7R)-7-isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene 
• 1572040-03-9 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylic acid dicyclohexylamide 
• 1572039-79-2 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylic acid (2,4,6-triisopropylphenyl)amide 
• 1572040-06-2 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylic acid (2,4,6-trimethylphenyl)amide 
• 1572040-05-1 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylic acid phenylamide 

Relevant academic research and scientific papers

A synthesis method of V-type organic ligand is disclosed. Synthetic V-type organic ligand and application thereof

The invention discloses a synthesis method of V-type organic ligand, relates to the technical field of organic ligands, and comprises the following steps: A (B dimethylaminopropyl) 1 - ethylcarbodiimide hydrochloride, 3 -hydroxybenzotriazole and -3 - N, N

A nordehydroabietyl amide-containing chiral diene for rhodium-catalysed asymmetric arylation to nitroolefins

A highly enantioselective rhodium catalysed asymmetric arylation (RCAA) of nitroolefins with arylboronic acids is presented using a newly developed, C1-symmetric, non-covalent interacted, phellandrene derived, nordehydroabietyl amide-containing chiral diene under mild conditions. Stereoelectronic effects were studied, suggesting an activation of the bound substrate through the secondary amide as a hydrogen-bond donor.

CHIRAL BICYCLIC DIENE LIGAND HAVING HYDROGEN BOND FORMATION AMIDE GROUP

PROBLEM TO BE SOLVED: To provide a chiral bicyclic diene ligand having a tert-butylamide group contributing to the formation of hydrogen bond, and a chiral transition metal complex for efficiently obtaining optically active material. SOLUTION: This invention relates to a chiral bicyclic diene ligand represented by formula (1), and a chiral late transition metal complex purified by a reaction formula represented by formula (2), wherein R1-R3 are H, an alkyl group, or an alkoxy group; n is 0 or 1 methylene chain; M is a late transition metal; and L is a ligand replaceable with a ligand of formula (1). COPYRIGHT: (C)2016,JPOandINPIT

Gold meets rhodium: Tandem one-pot synthesis of β-disubstituted ketones via meyer-schuster rearrangement and asymmetric 1,4-addition

An asymmetric one-pot tandem Au/Rh-catalyzed synthesis of highly enantioenriched β-disubstituted ketones starting from racemic propargyl alcohols is disclosed. The compatibility of the two metal complexes (Au/Rh) and their orthogonal ligand systems (NHC/d

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

Rhodium-catalyzed asymmetric arylation of imines using electronically and sterically-modified chiral diene ligands gave the corresponding diarylmethylamines in high yield and with high enantioselectivity using just 0.3 mol% of catalyst.