1188966-75-7

Basic information

• Product Name: 2-Naphthyl (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylate
• Synonyms: 2-Naphthyl (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylate ;2-Naphthyl (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylate 97%
• CAS NO: 1188966-75-7
• Molecular Formula: C23H24O2
• Molecular Weight: 332.43546
• Mol File: 1188966-75-7.mol
• Article Data: 5

Chemical Properties

• Melting Point: 90-94°C
• Boiling Point: 485.2±40.0 °C(Predicted)
• Appearance: /
• Density: 1.127±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2-Naphthyl (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Naphthyl (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylate(1188966-75-7)
• EPA Substance Registry System: 2-Naphthyl (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylate(1188966-75-7)

Safety Data

• Hazard Codes: N
• Statements: 50/53
• Safety Statements: 60-61
• RIDADR: UN 3077 9 / PGIII
• WGK Germany: 2
• Hazardous Substances Data: 1188966-75-7(Hazardous Substances Data)

Upstream product

• 91805-17-3 naphthalen-2-yl prop-2-ynoate 
• 1184-58-3 dimethylaluminum chloride 
• 4221-98-1 (R)-5-isopropyl-2-methylcyclohexa-1,3-diene 
• 99-83-2 p-mentha-1,5-diene 
• 135-19-3 β-naphthol 
• 1252606-18-0 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octane-2,5-diene-2-carboxylic acid 

Downstream Products

• 1063949-39-2 (1R,4R,7R)-7-isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene 
• 1572040-03-9 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylic acid dicyclohexylamide 
• 1572039-79-2 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylic acid (2,4,6-triisopropylphenyl)amide 
• 1572040-06-2 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylic acid (2,4,6-trimethylphenyl)amide 
• 1572040-05-1 (1R,4R,7R)-7-isopropyl-5-methylbicyclo[2.2.2]octa-2,5-diene-2-carboxylic acid phenylamide 

Relevant articles and documents

A synthesis method of V-type organic ligand is disclosed. Synthetic V-type organic ligand and application thereof

The invention discloses a synthesis method of V-type organic ligand, relates to the technical field of organic ligands, and comprises the following steps: A (B dimethylaminopropyl) 1 - ethylcarbodiimide hydrochloride, 3 -hydroxybenzotriazole and -3 - N, N

CHIRAL BICYCLIC DIENE LIGAND HAVING HYDROGEN BOND FORMATION AMIDE GROUP

PROBLEM TO BE SOLVED: To provide a chiral bicyclic diene ligand having a tert-butylamide group contributing to the formation of hydrogen bond, and a chiral transition metal complex for efficiently obtaining optically active material. SOLUTION: This invention relates to a chiral bicyclic diene ligand represented by formula (1), and a chiral late transition metal complex purified by a reaction formula represented by formula (2), wherein R1-R3 are H, an alkyl group, or an alkoxy group; n is 0 or 1 methylene chain; M is a late transition metal; and L is a ligand replaceable with a ligand of formula (1). COPYRIGHT: (C)2016,JPOandINPIT

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

Rhodium-catalyzed asymmetric arylation of imines using electronically and sterically-modified chiral diene ligands gave the corresponding diarylmethylamines in high yield and with high enantioselectivity using just 0.3 mol% of catalyst.