1188967-40-9Relevant academic research and scientific papers
Highly enantioselective synthesis of (diarylmethyl)amines by rhodium-catalyzed arylation of N-nosylimines using a chiral bicyclo[3.3.0]diene ligand
Wang, Li,Wang, Zhi-Qian,Xu, Ming-Hua,Lin, Guo-Qiang
experimental part, p. 3263 - 3267 (2010/11/18)
A highly efficient asymmetric arylation of N-nosylimines with arylboronic acids catalyzed by a rhodium-diene complex is described. A wide range of enantiopure (98-99% ee) N-(diarylmethyl)nosylamides, as well as (3S)-2-(4-nosyl)-3-phenylisoindolin-1-one, were obtained in high yields (83-99%) under very mild conditions. Georg Thieme Verlag Stuttgart New York.
Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines
Okamoto, Kazuhiro,Hayashi, Tamio,Rawal, Viresh H.
supporting information; experimental part, p. 4815 - 4817 (2009/12/08)
Rhodium-catalyzed asymmetric arylation of imines using electronically and sterically-modified chiral diene ligands gave the corresponding diarylmethylamines in high yield and with high enantioselectivity using just 0.3 mol% of catalyst.
