118916-46-4

Upstream product

• 931-59-9 benzenesulfenyl chloride 
• 13265-84-4 D-glucal 
• 100-39-0 benzyl bromide 
• 116454-02-5 1,5-Anhydro-3,4,6-tri-O-benzyl-1,2-didesoxy-2-phenylthio-D-arabino-hex-1-enitol 
• 80040-79-5 3,4,6-tri-O-benzyl-D-galactal 
• 125710-62-5 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-phenylthio-D-lyxo-hex-1-enitol 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 

Downstream Products

• 125612-03-5 3,7-anhydro-5,6,8-tri-O-benzyl-4-deoxy-4-phenylsulfinyl-D-talo-oct-3-enose diethylacetal 
• 125612-03-5 3,7-anhydro-5,6,8-tri-O-benzyl-4-deoxy-4-phenylsulfinyl-D-galacto-oct-3-enose diethylacetal 
• 118798-71-3 2,6-Anhydro-1,3,4-tri-O-benzyl-5-desoxy-8,9:10,11-di-O-isopropyliden-5-phenylsulfinyl-D-manno-D-arabino-undec-5-enitol 
• 118798-71-3 2,6-Anhydro-1,3,4-tri-O-benzyl-5-desoxy-8,9:10,11-di-O-isopropyliden-5-phenylsulfinyl-L-gulo-D-arabino-undec-5-enitol 
• 136034-19-0 (2S,4S,4aS,6R,7R,8S,8aR)-7,8-Bis-benzyloxy-6-benzyloxymethyl-2,4-diphenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 136034-22-5 2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol 
• 794488-76-9 C-[(R)-C-Phenyl-C-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)]-methylamine 
• 105938-05-4 (S)-((4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-phenyl-methanol 
• 768385-87-1 [(R)-Phenyl-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yl)-methyl]-carbamic acid tert-butyl ester 
• 136034-26-9 (2S,3R,4R,5S,6R)-2-((R)-Amino-phenyl-methyl)-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol; compound with trifluoro-acetic acid 
• 768385-86-0 [(R)-Phenyl-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-methyl]-carbamic acid tert-butyl ester 
• 105539-37-5 (E)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-1-deoxy-1-phenyl-D-gluco-hept-1-enitol 
• 136034-23-6 β-D-Glucopyranosylphenylmethane 
• 136087-41-7 (R)-[(4S,5R,6R)-3-((S)-Benzenesulfinyl)-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl]-phenyl-methanol 

Relevant academic research and scientific papers

Synthesis of the basic structure of Ezomycin A

Direct 1-C-lithiation of the readily available 2-phenylsulfinyl-D-galactals 3h, l leads to reactive intermediate, which on reaction with glyoxal monodiethylacetal as electrophile yield compounds 7.Subsequent O-benzylation of the unprotected hydroxy group,

SYNTHESIS OF CARBON BRIDGED C-DISACCHARIDES

Direct lithiation of the readily available 2-phenylsulfinyl-D-glucal 2 provides the 1-C-lithiated species 2A furnishing with 4-deoxy-4-formyl-D-glucose derivative 7 in a diastereocontrolled reaction the C-disaccharide intermediate 8.This compound is trans

Functionally Substituted Vinyl Carbanions, 38. - C-Glucosides by Direct 1-C-Lithiation of 2-Phenylsulfinyl-Activated D-Glucal

Direct 1-C-lithiation of the readily available 2-phenylsulfinyl-D-glucals 6,h,l leads to reactive intermediates furnishing with aldehydes as electrophiles the compounds 7 in high yields.Subsequent removal of the phenylsulfinyl group with Raney nickel and