1189241-04-0

Basic information

• Product Name: (R)-3-(4-fluorophenyl)-3-methylcyclohexanone
• Synonyms: (R)-3-(4-fluorophenyl)-3-methylcyclohexanone
• CAS NO: 1189241-04-0
• Molecular Weight: 206.26
• Mol File: 1189241-04-0.mol

Chemical Properties

• CAS DataBase Reference: (R)-3-(4-fluorophenyl)-3-methylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-(4-fluorophenyl)-3-methylcyclohexanone(1189241-04-0)
• EPA Substance Registry System: (R)-3-(4-fluorophenyl)-3-methylcyclohexanone(1189241-04-0)

Safety Data

• Hazardous Substances Data: 1189241-04-0(Hazardous Substances Data)

Upstream product

• 1193-18-6 3-methylcyclohexen-2-one 
• 25776-12-9 sodium tetrakis(4-fluorophenyl)borate 
• 448-59-9 tris(4-fluorophenyl)boroxine 
• 1765-93-1 4-fluoroboronic acid 

Relevant articles and documents

Synthesis of diverse β-quaternary ketones via palladium-catalyzed asymmetric conjugate addition of arylboronic acids to cyclic enones

Abstract The development and optimization of a palladium-catalyzed asymmetric conjugate addition of arylboronic acids to cyclic enone conjugate acceptors is described. These reactions employ air-stable and readily-available reagents in an operationally si

Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to five-, six-, and seven-membered β-substituted cyclic enones: enantioselective construction of all-carbon quaternary stereocenters

The first enantioselective Pd-catalyzed construction of all-carbon quaternary stereocenters via 1,4-addition of arylboronic acids to β-substituted cyclic enones is reported. Reaction of a wide range of arylboronic acids and cyclic enones using a catalyst

Chiral tetrafluorobenzobarrelenes as effective ligands for rhodium-catalyzed asymmetric 1,4-addition of arylboroxines to β,β-disubstituted α,β-unsaturated ketones

(Chemical Equotion Present) Lock, Stock and Two Smoking Barrelenes: The rhodium-catalyzed 1,4-addition of readily available arylboronic acid anhydrides to simple β,β-disubstituted α,βunsaturated ketones creates quaternary carbon stereocenters with high enantiomeric excesses using a chiral tetrafluorobenzobarrelene ligand.

Sodium tetraarylborates as effective nucleophiles in rhodium/diene- catalyzed 1,4-addition to β,β-disubstituted α,β-unsaturated ketones: Catalytic asymmetric construction of quaternary carbon stereocenters

(Chemical Equation Presented) A rhodium-catalyzed 1,4-addition of sodium tetraarylborates to β,β-disubstituted α,β-unsaturated ketones is described. Highly efficient asymmetric catalysis has also been achieved by employing a readily available chiral diene