118946-86-4Relevant academic research and scientific papers
The Chemistry of 3-(α-Cyanobenzylidene)-1-phenyltriazenes and Their Conversion to Diarylmaleimides and Phenanthrene-9,10-dicarboximides
Smith, Peter A. S.,Friar, James Jeffrey,Resemann, Wolfgang,Watson, Andrew C.
, p. 3351 - 3362 (2007/10/02)
3-(α-Cyanobenzylidene)-1-phenyltriazine (3a), the product of thermolysis of 5-azido-1,4-diphenyl-1,2,3-triazole (2), is attacked by nucleophilic reagents at the azomethine carbon.Alcohols and phenol give rise to acetals of the N-phenylamidine of phenylgly
SYNTHESIS AND THERMOLYSIS OF 4-SUBSTITUTED 5-AZIDO-1-PHENYL-1,2,3-TRIAZOLES
L'abbe, Gerrit,Vandendriessche, Anna,Toppet, Suzanne
, p. 3617 - 3626 (2007/10/02)
5-Azido-1-phenyltriazoles (4) can thermally isomerize to diazo substituted tetrazoles (5) or decompose to alkylidenetriazenes (8) depending on the nature of the substituent at the 4-position.The former are obtained for electron-withdrawing substituents (C
