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118964-06-0

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118964-06-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 118964-06-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,8,9,6 and 4 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 118964-06:
(8*1)+(7*1)+(6*8)+(5*9)+(4*6)+(3*4)+(2*0)+(1*6)=150
150 % 10 = 0
So 118964-06-0 is a valid CAS Registry Number.

118964-06-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name (-)-aphanorphine

1.2 Other means of identification

Product number -
Other names (1R,9R)-1,10-Dimethyl-10-aza-tricyclo[7.2.1.02,7]dodeca-2,4,6-trien-4-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:118964-06-0 SDS

118964-06-0Downstream Products

118964-06-0Relevant articles and documents

Enantiomerically Enriched α-Borylzinc Reagents by Nickel-Catalyzed Carbozincation of Vinylboronic Esters

Zhang, Chenlong,Hu, Weipeng,Lovinger, Gabriel J.,Jin, Jing,Chen, Jingjia,Morken, James P.

, p. 14189 - 14195 (2021/09/11)

In this paper is described a synthesis of enantiomerically enriched, configurationally stable organozinc reagents by catalytic enantioselective carbozincation of a vinylboronic ester. This process furnishes enantiomerically enriched α-borylzinc intermediates that are shown to undergo stereospecific reactions, producing enantioenriched secondary boronic ester products. The properties of the intermediate α-borylzinc reagent are probed and the synthetic utility of the products is demonstrated by application to the synthesis of (-)-aphanorphine and (-)-enterolactone.

An effective route to (-)-aphanorphine using D-tyrosine as a chiral building block

Li, Min,Zhou, Peijie,Roth, Hans F.

, p. 55 - 60 (2007/12/31)

A stereoselective approach toward a naturally occurring alkaloid, (-)-aphanorphine, has been achieved via a series of reactions from Boc-D-tyrosine. Georg Thieme Verlag Stuttgart.

Synthesis of (-)-aphanorphine using aryl radical cyclization.

Tamura,Yanagimachi,Kobayashi,Ishibashi

, p. 2427 - 2429 (2007/10/03)

[structure: see text] The synthesis of (-)-aphanorphine was achieved by using Bu(3)SnH-mediated aryl radical cyclization of 1-benzyloxycarbonyl-2-(2-bromo-4-methoxyphenylmethyl)-2-methoxycarbonyl-4-(phenylthiomethylene)pyrrolidine, leading to exclusive fo

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