118967-74-1

Basic information

• Product Name: 1-(4,6-di-O-acetyl-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)-2-hydroxybenzene
• CAS NO: 118967-74-1
• Molecular Weight: 306.315
• Mol File: 118967-74-1.mol

Chemical Properties

• CAS DataBase Reference: 1-(4,6-di-O-acetyl-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)-2-hydroxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4,6-di-O-acetyl-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)-2-hydroxybenzene(118967-74-1)
• EPA Substance Registry System: 1-(4,6-di-O-acetyl-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)-2-hydroxybenzene(118967-74-1)

Safety Data

• Hazardous Substances Data: 118967-74-1(Hazardous Substances Data)

Upstream product

• 157905-00-5 phenyl 4,6-di-O-acetyl-2,3-dideoxy-α/β-D-erythro-hex-2-enopyranoside 
• 2873-29-2 D-glucal triacetate 
• 108-95-2 phenol 

Relevant articles and documents

Reaction of 2,3-unsaturated aryl glycosides with Lewis acids: A convenient entry to C-aryl glycosides

A facile synthesis of 2',3'-unsaturated-C-aryl glycosides by BF3 · Et2O mediated 'O' to 'C' transformation of 2,3-unsaturated aryl glycosides is reported.

STEREOSELECTIVE ARYLATION OF PYRANOID GLYCALS, USING BROMOMAGNESIUM PHENOLATES : AN ENTRY TO 2,3-UNSATURATED C-α-GLYCOPYRANOSYLARENES

The arylation of acetylated pyranoid glycals at C-1 by means of bromomagnesium phenolates provides a highly stereoselective entry to 1-C-α-glycopyranosyl-2-hydroxyarenes.

A SIMPLE DIASTEREOSELECTIVE SYNTHESYS OF 2',3'-UNSATURATED ARYL C-GLUCOPYRANOSIDES

The regio- and stereoselective arylation at the anomer center of 3,4,5,-tri-O-acetyl-D-glucal (2) by means of bromomagnesium phenolates (1) allows direct preparation of 2',3'-unsaturated 1-C-aryl-α-D-glycosides (3).