118968-07-3Relevant academic research and scientific papers
SYNTHETIC STUDIES ON ANTIBIOTIC VALIDAMYCINS. PART 12. TOTAL SYNTHESIS OF (+)-VALIDAMYCIN B AND (+)-VALIDOXYLAMINE B
Ogawa, Seiichiro,Miyamoto, Yasunobu,Nose, Taisuke
, p. 2675 - 2680 (2007/10/02)
The first complete synthesis of validamycin B (1a) and validoxylamine B (2a) is reported; coupling of the epoxide (12) and the partially protected derivative (16) of (+)-valienamine, followed by deprotection, gives (1a), which was identified from the 1H n
