118968-15-3Relevant academic research and scientific papers
PHOTOSUBSTITUTION OF DICYANOBENZENES BY GROUP 14 ORGANOMETALLIC COMPOUNDS VIA PHOTOINDUCED ELECTRON-TRANSFER. ADDITIVE AND MEDIUM EFFECTS ON PHOTOINDUCED ELECTRON TRANSFER REACTION
Mizuno, Kazuhiko,Nakanishi, Kazuhisa,Otsuji, Yoshio
, p. 1833 - 1836 (1988)
The phenanthrene-sensitized photoreaction of 1,2- and 1,4-dicyanobenzenes with group 14 organometallic compounds containing allylic and benzylic groups in CH3CN afforded the corresponding 1- and 4-allylated benzonitriles in high yields.These photoreactions were accelerated by the addition of Mg(ClO4)2 and benzene derivatives.
Cp*Co(III)-Catalyzed γ-Selective C-H Allylation/Hydroamination Cascade for the Synthesis of Dihydroisoquinolines
Choi, Suh Young,Kim, Hyeon Dae,Park, Jong-Un,Park, Sun-A,Kim, Ju Hyun
, p. 10038 - 10042 (2019)
A Cp*Co(III)-catalyzed γ-selective C-H allylation/hydroamination cascade toward the synthesis of 3,4-dihydroisoquinolines (DHIQs) has been successfully developed, starting from NH ketimines and allyl carbonates. Notably, highly efficient and γ-selective C-H allylations were accomplished using γ-substituted allyl reagents, thus overcoming the issues of poor α/γselectivity and low reactivity of previous transition metal-catalyzed C-H allylations. The stereochemistry of allyl carbonates was a crucial factor, and synthesis of the DHIQs was achieved using (Z)-allyl carbonates.
Photosubstitution of Dicyanobenzenes by Allylic Silanes, Germanes, and Stannanes via Photoinduced Electron Transfer
Nakanishi, Kazuhisa,Mizuno, Kazuhiko,Otsuji, Yoshio
, p. 2371 - 2379 (2007/10/02)
Photoreactions of 1,2- and 1,4-dicyanobenzenes (o- and p-DCB) with allylic silanes, germanes, and stannanes in acetonitrile were studied under various conditions.In these photoreactions, one of cyano groups of o- and p-DCB was replaced by allylic groups.W
