212626-89-6

Basic information

• Product Name: 2-(2-bromophenyl)-2-methylpropionaldehyde
• Synonyms: 2-(2-bromophenyl)-2-methylpropionaldehyde
• CAS NO: 212626-89-6
• Molecular Weight: 227.101
• Mol File: 212626-89-6.mol

Chemical Properties

• CAS DataBase Reference: 2-(2-bromophenyl)-2-methylpropionaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-bromophenyl)-2-methylpropionaldehyde(212626-89-6)
• EPA Substance Registry System: 2-(2-bromophenyl)-2-methylpropionaldehyde(212626-89-6)

Safety Data

• Hazardous Substances Data: 212626-89-6(Hazardous Substances Data)

Upstream product

• 57775-06-1 2-(2-bromophenyl)-2-methylpropanenitrile 
• 177748-64-0 2-(2-bromophenyl)-2-methylpropan-1-ol 
• 177748-63-9 methyl 2-(2-bromophenyl)-2-methylpropanoate 

Downstream Products

• 118968-15-3 2-(1,1-dimethyl-2-propenyl)benzonitrile 
• 177748-64-0 2-(2-bromophenyl)-2-methylpropan-1-ol 
• 1069114-48-2 (2-(2-bromophenyl)-2-methylpropoxy)triisopropylsilane 
• 57625-74-8 methyl 2-methyl-2-phenylpropionate 
• 98-83-9 isopropenylbenzene 
• 1206451-49-1 8,8-dimethylbicyclo[4.2.0]octa-1,3,5-trien-7-one 

Relevant articles and documents

Intramolecular Anti-Carbolithiation of Alkynes: Stereo-Directing Effect of Lithium-Coordinating Substituents

This paper presents the results of our investigations on the stereochemical course of intramolecular carbolithiation of alkynes. It is shown that the presence of a lithium-chelating propargylic substituent completely reverses the otherwise favored syn-pro

Chiral Magnesium Bisphosphate-Catalyzed Asymmetric Double C(sp3)-H Bond Functionalization Based on Sequential Hydride Shift/Cyclization Process

Described herein is a chiral magnesium bisphosphate-catalyzed asymmetric double C(sp3)-H bond functionalization triggered by a sequential hydride shift/cyclization process. This reaction consists of stereoselective domino C(sp3)-H bond functionalization: (1) a highly enantio- and diastereoselective C(sp3)-H bond functionalization by chiral magnesium bisphosphate (first [1,5]-hydride shift), and (2) a highly diastereoselective C(sp3)-H bond functionalization by an achiral catalyst (Yb(OTf)3, second [1,5]-hydride shift).

Pd-catalyzed intramolecular acylation of aryl bromides via C-H functionalization: A highly efficient synthesis of benzocyclobutenones

(Chemical Equation Presented) A new catalyst system for the intramolecular acylation of aldehydes with aryl bromides via C-H functionalization is described. The transformation is distinguished by a remarkable functional group tolerance and hence allows fo