119005-82-2

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 246852-75-5 (1S,3S,4S,5R,6R,8S)-4,5-Bis-benzyloxy-1-methyl-2,7,9,10-tetraoxa-tricyclo[4.3.2.0^3,8]undecane 
• 119005-81-1 1,6-anhydro-2-O-allyl-β-D-mannopyranose 
• 14168-65-1 mannosan 
• 66963-52-8 (1R,2R,3S,4S,5R)-2,3-Bis-benzyloxy-4-[((E)-propenyl)oxy]-6,8-dioxa-bicyclo[3.2.1]octane 
• 66963-51-7 (1R,2R,3S,4S,5R)-4-Allyloxy-2,3-bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]octane 
• 100-39-0 benzyl bromide 
• 136944-92-8 1,2-O-(Allyloxyethyliden)-β-D-mannopyranose 
• 100-44-7 benzyl chloride 
• 108-24-7 acetic anhydride 
• 67227-89-8 1,6-anhydro-3,4-di-O-benzyl-β-D-mannopyranoside 
• 29073-91-4 1,2-O-(1-methoxyethylidene)-β-D-mannopyranose 

Relevant academic research and scientific papers

Formation of the 1,2,6-orthoester of mannose and its utilization in the glycosylation reaction

The synthesis of mannose 1,2,6-orthoester and its utilization in the glycosylation reaction are described.

Glycosylation using a one-electron-transfer, homogeneous reagent. Application to an efficient synthesis of the trimannosyl core of N-glycosylproteins

Double glycosylation of methyl 2,4-di-O-benzyl-β-D-mannopyranoside with ethyl 2-O-benzoyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside using as promoter tris(4-bromophenyl)ammoniumyl hexachloroantimonate, a stable, commercial, and crystalline radical cat

Facile Preparation of 3,4-Di-O-acetyl-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose and Some Derivatives Thereof: Useful Precursors for Oligosaccharide Synthesis

A facile, virtually one-pot synthesis of the title compound and also some of its derivatives is based on regioselective 2-substitutions of 1,6-anhydro-β-D-mannopyranose using stannylidene activation.The compounds thus prepared are useful precursors in the synthesis of glycoprotein-type oligosaccharides.